81764-12-7

Basic information

• Product Name: c-2-hydroxy-t-2-methyl-c-5-t-butylcyclohexan-r-1-yliodoacetate
• CAS NO: 81764-12-7
• Molecular Weight: 354.228
• Mol File: 81764-12-7.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: c-2-hydroxy-t-2-methyl-c-5-t-butylcyclohexan-r-1-yliodoacetate(CAS DataBase Reference)
• NIST Chemistry Reference: c-2-hydroxy-t-2-methyl-c-5-t-butylcyclohexan-r-1-yliodoacetate(81764-12-7)
• EPA Substance Registry System: c-2-hydroxy-t-2-methyl-c-5-t-butylcyclohexan-r-1-yliodoacetate(81764-12-7)

Safety Data

• Hazardous Substances Data: 81764-12-7(Hazardous Substances Data)

Upstream product

• 3419-74-7 4-tert-Butyl-1-methylcyclohex-1-en 
• 563-68-8 thallium(I) acetate 

Downstream Products

• 5951-25-7 1-methyl-c-4-t-butylcyclohexane-r-1-c-2-diol 

Relevant articles and documents

Reactions of 1-Methyl-4-t-butylcyclohexene and 1-Methylcyclohexene with Thallium(I) Acetate-Iodine

Treatment of 1-methyl-4-t-butylcyclohexene (2) with thallium(I)acetate-iodine in wet acetic acid at 90 deg C gives a complex mixture of products, which differs from that obtained from a Woodward reaction with silver(I) acetate followed by hydrolysis and which includes the unexpected hydroxy-iodoacetate (25).At 20 deg C the thallium(I)-mediated reaction gives a mixture of regioisomeric iodo-acetates.A re-investigation of the reaction of thallium(I) acetate-iodine with 1-methylcyclohexene (1) at 20 deg C has shown that this is not highly regioselective as reported earlier.The actions of KOAc-I2-18-crown-6 and iodine(III) triacetate in acetic acid on the alkenes (1) and (2), and of I2-H2O in tetramethylene sulphone-chloroform on the alkene (2) are reported.