81818-92-0Relevant articles and documents
Crossed aldol reaction using cross-linked polymer-bound lithium dialkylamide
Seki, Atsushi,Ishiwata, Fusae,Takizawa, Youichi,Asami, Masatoshi
, p. 5001 - 5011 (2007/10/03)
Cross-linked polymer-bound lithium dialkylamides were employed in crossed aldol reaction of various carbonyl compounds with aldehydes to afford the corresponding β-hydroxycarbonyl compounds. The introduction of spacer chains to the polymer-bound lithium d
HIGHLY ANTI DIASTEREOSELECTIVE REDUCTION OF 2-ALKYL-3-OXO AMIDES BY POTASSIUM TRIETHYLBOROHYDRIDE
Ito, Yoshio,Katsuki, Tsutomu,Yamaguchi, Masaru
, p. 4643 - 4646 (2007/10/02)
Potassium triethylborohydride was found to reduce 2-alkyl-3-oxo amides to the corresponding 3-hydroxy amides with excellent anti-diastereoselectivity (>99:1), and in combination with asymmetric acylation, a useful route to optically active anti-2-alkyl-3-