81837-96-9

Basic information

• Product Name: N-<1-(N,N-Dimethylthiocarbamoyl)-1-methylethyl>benzamid
• Synonyms: N-<1-(N,N-Dimethylthiocarbamoyl)-1-methylethyl>benzamid
• CAS NO: 81837-96-9
• Molecular Weight: 250.365
• Mol File: 81837-96-9.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: N-<1-(N,N-Dimethylthiocarbamoyl)-1-methylethyl>benzamid(CAS DataBase Reference)
• NIST Chemistry Reference: N-<1-(N,N-Dimethylthiocarbamoyl)-1-methylethyl>benzamid(81837-96-9)
• EPA Substance Registry System: N-<1-(N,N-Dimethylthiocarbamoyl)-1-methylethyl>benzamid(81837-96-9)

Safety Data

• Hazardous Substances Data: 81837-96-9(Hazardous Substances Data)

Upstream product

• 107640-46-0 2-(benzyloxycarboxamido)-N,N,2-trimethylpropionthioamid 
• 107640-45-9 2-(benzyloxycarbonyl)-N,N,2-trimethylpropionamid 
• 98-88-4 benzoyl chloride 
• 107640-47-1 N,N-Dimethyl-α-aminoisobutyrthioamid 
• 98-91-9 thiobenzoic acid 
• 54856-83-6 3-dimethylamino-2,2-dimethyl-2H-azirine 

Downstream Products

• 83569-35-1 4,4,7,7-Tetramethyl-2,9-diphenyl-1,6-dithia-3,8-diazaspiro<4,4>nona-2,8-dien 
• 84938-38-5 2,2,7,7-Tetramethyl-4,9-diphenyl-1,6-dithia-3,8-diazaspiro<4,4>nona-3,8-dien 
• 52755-69-8 4,4,9,9-Tetramethyl-2,7-diphenyl-1,6-dithia-3,8-diazaspiro<4,4>nona-2,7-dien 
• 81837-94-7 4,4-dimethyl-2-phenyl-1,3-thiazole-5(4H)-thione 

Relevant articles and documents

2,4-Bis(4-methylphenylthio)-1,3,2λ5,4λ5-dithiadiphosphetane-2,4-dithione: A New Reagent for Thiation of N,N-Disubstituted Amides

As a new reagent for the thiation of amides, the easily accessible 2,4-bis(4-methylphenylthio)-1,3,2λ5,4λ5-dithiadiphosphetane-2,4-dithione (9) shows a remarkable selectivity.This selectivity - the preferred thiation of N,N-disubstituted amides - is complementary to the one of the well known Lawesson reagent.Thiation of diamides of type 2 with 9 leads via cyclization of the corresponding dithiodiamides directly to 1,3-thiazole-5(4H)-thiones 1.

1,3-Dipolare Cycloadditionen von 2-(Benzonitrilio)-2-propanid mit 4,4-Dimethyl-2-phenyl-2-thiazolin-5-thion und Schwefelkohlenstoff

Irradiation of 2,2-dimethyl-3-phenyl-2H-azirine (11) in the presence of 4,4-dimethyl-2-phenyl-2-thiazolin-5-thione (7) yields a mixture of the three (1:1)-adducts 8, 12 and 13 (Schemes 3 and 6).The formation of 8 and 12 can be explained by 1,3-dipolar cyc