81864-05-3

Basic information

• Product Name: 2,3-diamino-5,6,7,8-tetrahydro-5,5,8,8-tetramethyl naphthalene
• Synonyms: 2,3-diamino-5,6,7,8-tetrahydro-5,5,8,8-tetramethyl naphthalene
• CAS NO: 81864-05-3
• Molecular Weight: 218.342
• Mol File: 81864-05-3.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 2,3-diamino-5,6,7,8-tetrahydro-5,5,8,8-tetramethyl naphthalene(CAS DataBase Reference)
• NIST Chemistry Reference: 2,3-diamino-5,6,7,8-tetrahydro-5,5,8,8-tetramethyl naphthalene(81864-05-3)
• EPA Substance Registry System: 2,3-diamino-5,6,7,8-tetrahydro-5,5,8,8-tetramethyl naphthalene(81864-05-3)

Safety Data

• Hazardous Substances Data: 81864-05-3(Hazardous Substances Data)

Upstream product

• 6683-46-1 1,1,4,4-Tetramethyl-1,2,3,4-tetrahydro-naphthalene 

Downstream Products

• 155877-88-6 methyl 4-(1H-2,3,7,8,9,10-hexahydro-1,7,7,10,10-pentamethyl-2-oxonaphtho<2,3-b><1,4>diazepin-4-yl)benzoate 
• 155877-85-3 methyl 4-(1H-2,3,7,8,9,10-hexahydro-7,7,10,10-tetramethyl-2-oxonaphtho<2,3-b><1,4>diazepin-4-yl)benzoate 

Relevant articles and documents

C-H Amination of Arenes with Hydroxylamine

This Letter describes the development of a TiIII-mediated reaction for the C-H amination of arenes with hydroxylamine. This reaction is applied to a variety of electron-rich (hetero)arene substrates, including a series of natural products and pharmaceuticals. It offers the advantages of mild conditions (room temperature), fast reaction rates (30 min), compatibility with ambient moisture and air, scalability, and the use of inexpensive commercial reagents.