81912-53-0

Basic information

• Product Name: 4(S)-(methoxycarbonyl)-N-benzoyl-1,3-oxazolidine-2-thione
• Synonyms: 4(S)-(methoxycarbonyl)-N-benzoyl-1,3-oxazolidine-2-thione
• CAS NO: 81912-53-0
• Molecular Weight: 265.29
• Mol File: 81912-53-0.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: 4(S)-(methoxycarbonyl)-N-benzoyl-1,3-oxazolidine-2-thione(CAS DataBase Reference)
• NIST Chemistry Reference: 4(S)-(methoxycarbonyl)-N-benzoyl-1,3-oxazolidine-2-thione(81912-53-0)
• EPA Substance Registry System: 4(S)-(methoxycarbonyl)-N-benzoyl-1,3-oxazolidine-2-thione(81912-53-0)

Safety Data

• Hazardous Substances Data: 81912-53-0(Hazardous Substances Data)

Upstream product

• 75-15-0 carbon disulfide 
• 2788-84-3 (S)-serine methyl ester 
• 98-88-4 benzoyl chloride 
• 108082-28-6 4(S)-(methoxycarbonyl)-1,3-oxazolidine-2-thione 

Downstream Products

• 1485-70-7 N-benzylbenzamide 
• 1464-98-8 N-(prop-2-yn-1-yl)benzamide 
• 64792-80-9 2-(benzoylamino)acetaldehyde dimethyl acetal 
• 5440-69-7 N-isopropylbenzamide 
• 2772-60-3 N-octylbenzamide 
• 77278-38-7 4-benzoylpiperazine-1-carboxylic acid tert-butyl ester 
• 1468-28-6 4-benzoylmorpholine 
• 776-75-0 N-benzoylpiperidine 
• 3389-54-6 n-benzoylpyrrolidine 
• 27110-61-8 N-(2-Bromo-ethyl)-benzamide 
• 3005-61-6 methyl (S)-2-(benzoylamino)-3-phenylpropanoate 
• 93-99-2 benzoic acid phenyl ester 
• 1523-17-7 4-bromophenyl benzoate 
• 1523-19-9 4-methoxyphenyl benzoate 

Relevant articles and documents

Metal-Free Selective Modification of Secondary Amides: Application in Late-Stage Diversification of Peptides

Here we solve a long-standing challenge of the site-selective modification of secondary amides and present a simple two-step, metal-free approach to selectively modify a particular secondary amide in molecules containing multiple primary and secondary amides. Density functional theory (DFT) provides insight into the activation of C-N bonds. This study encompasses distinct chemical advances for late-stage modification of peptides thus harnessing the amides for the incorporation of various functional groups into natural and synthetic molecules.

A NEW CHIRAL RECOGNITION IN AMINOLYSIS OF 3-ACYL-4(R)-METHOXYCARBONYL-1,3-THIAZOLIDINE-2-THIONE WITH RACEMIC AMINES

A chiral recognition was observed in aminolysis of 3-acyl-4(R)-methoxycarbonyl-1,3-thiazolidine-2-thione 1 by racemic amine 2 to give an optically active amide (S-excess) and amine (R-excess).