82044-96-0

Basic information

• Product Name: (R)-(-)-2-Methyl-5-<1-(chlormethyl)vinyl>cyclohex-2-enon
• Synonyms: (R)-(-)-2-Methyl-5-<1-(chlormethyl)vinyl>cyclohex-2-enon
• CAS NO: 82044-96-0
• Molecular Weight: 184.666
• Mol File: 82044-96-0.mol
• Article Data: 19

Chemical Properties

• CAS DataBase Reference: (R)-(-)-2-Methyl-5-<1-(chlormethyl)vinyl>cyclohex-2-enon(CAS DataBase Reference)
• NIST Chemistry Reference: (R)-(-)-2-Methyl-5-<1-(chlormethyl)vinyl>cyclohex-2-enon(82044-96-0)
• EPA Substance Registry System: (R)-(-)-2-Methyl-5-<1-(chlormethyl)vinyl>cyclohex-2-enon(82044-96-0)

Safety Data

• Hazardous Substances Data: 82044-96-0(Hazardous Substances Data)

Upstream product

• 6485-40-1 (R)-Carvone 
• 870245-36-6 (R)-5-[3-(3-methoxyphenoxy)prop-1-en-2-yl]-2-methylcyclohex-2-en-1-one 
• 870245-35-5 (R)-5-[3-(3-hydroxyphenoxy)prop-1-en-2-yl]-2-methylcyclohex-2-en-1-one 
• 870245-38-8 (R)-5-[3-(3-benzoyloxyphenoxy)prop-1-en-2-yl]-2-methylcyclohex-2-en-1-one 
• 870245-37-7 (R)-5-[3-(3-isopropoxyphenoxy)prop-1-en-2-yl]-2-methylcyclohex-2-en-1-one 

Downstream Products

• 136066-42-7 (5R)-5-(1-Hexen-2-yl)-2-methyl-2-cyclohexen-1-one 
• 912279-69-7 (R)-5-{1-[4-(2-Methoxy-phenyl)-piperazin-1-ylmethyl]-vinyl}-2-methyl-cyclohex-2-enone 
• 145307-22-8 (4R,4aS,6R,7S,7aR)-2,4,7-trimethyloctahydro-1H-cyclopenta[c]pyridin-6-ol 
• 823788-09-6 bis[(4R,4aS,6R,7S,7aR)-2,4,7-trimethyloctahydro-1H-cyclopenta[c]pyridin-6-yl] 2,4-bis(3-methoxy-4-{[(4-methylphenyl)sulfonyl]oxy}phenyl)cyclobutane-1,3-dicarboxylate 
• 151894-32-5 (R)-(-)-Essigsaeure-<2-(4-methyl-5-oxo-cyclohex-3-enyl)allyl>ester 

Relevant articles and documents

Newly synthesized (R)-carvone-derived 1,2,3-triazoles: structural, mechanistic, cytotoxic and molecular docking studies

In the current study, natural (R)-carvone was used as starting material for the efficient synthesis of several 1,2,3-triazole derivatives. The produced products were obtained in good yields and characterized by 1H and 13C NMR and HRM

Type-II Pauson-Khand reaction of 1,8-enyne in the attempt of building 7/5 ring of (-)-caribenol A and DFT understanding

An attempt to access the fused 7/5 ring of the highly biologically active terpenoid caribenol A by employing intramolecular Pauson-Khand reaction of 1,8-enyne gave bridged 8-5 ring, the type-II Pauson-Khand reaction product. DFT study has been carried out

SYNTHESIS OF THAPSIGARGIN, NORTRILOBOLIDE, AND ANALOGS THEREOF

The present invention relates to the preparation of compounds of Formula I, including thapsigargin, nortrilobolide and 8-O-debutanoyl-thapsigargin from commercially available (R)-(-)-carvone via synthetic intermediate compound of formula 12 by pinacol coupling and in situ lactonization.