820994-17-0

Basic information

• Product Name: 1-Pyrrolidinecarboxylic acid, 2-[(1Z)-3-methoxy-3-oxo-1-propenyl]-, phenylmethyl ester, (2S)-
• CAS NO: 820994-17-0
• Molecular Formula: C16H19NO4
• Molecular Weight: 289.331
• Mol File: 820994-17-0.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 1-Pyrrolidinecarboxylic acid, 2-[(1Z)-3-methoxy-3-oxo-1-propenyl]-, phenylmethyl ester, (2S)-(CAS DataBase Reference)
• NIST Chemistry Reference: 1-Pyrrolidinecarboxylic acid, 2-[(1Z)-3-methoxy-3-oxo-1-propenyl]-, phenylmethyl ester, (2S)-(820994-17-0)
• EPA Substance Registry System: 1-Pyrrolidinecarboxylic acid, 2-[(1Z)-3-methoxy-3-oxo-1-propenyl]-, phenylmethyl ester, (2S)-(820994-17-0)

Safety Data

• Hazardous Substances Data: 820994-17-0(Hazardous Substances Data)

Upstream product

• 6216-63-3 N-Cbz-Prolinol 
• 71461-30-8 (S)-2-formylpyrrolidine-1-carboxylic acid benzyl ester 
• 88738-78-7 bis-(2,2,2-trifluoroethyl)(methoxycarbonylmethyl)phosphonate 

Downstream Products

• 543690-37-5 (1R,2S,7aS)-1,2-hydroxypyrrolizidine 
• 820994-20-5 methyl (2R,3S)-2,3-dihydroxy-3-[(2'S)-N-benzyloxycarbonylpyrrolidin-2'-yl]propanoate 
• 820994-19-2 methyl (2S,3R)-2,3-dihydroxy-3-[(2'S)-N-benzyloxycarbonylpyrrolidin-2'-yl]propanoate 

Relevant articles and documents

Polyhydroxylated pyrrolizidines. Part 5: Stereoselective synthesis of 1,2-dihydroxypyrrolizidines as a model for the preparation of densely polyhydroxylated pyrrolizidines

The reaction of N-benzyloxycarbonyl-l-prolinal 5 with (methoxycarbonylmethylene)triphenylphosphorane in CH2Cl2 afforded methyl (E)-3-[(2′S)-N-benzyloxycarbonylpyrrolidin-2′-yl] propenoate 7. When the reaction was performed in MeOH, a