82136-11-6Relevant articles and documents
Asymmetric Induction during Organometallic Conjugate Addition to Enantiomerically Pure 2-(Arylsulfinyl)-2-cyclopentenones
Posner, Gary H.,Mallamo, John P.,Hulce, Martin,Frye, Leah L.
, p. 4180 - 4185 (2007/10/02)
Virtually complete asymmetric induction is achieved during methyl-, vinyl- and naphthylmetallic conjugate addition to enantiomerically pure (S)-(+)-2-(p-tolylsulfinyl)-2-cyclopentenone ((S)-(+)-1). (R)-3-Methylcyclopentanone is obtained when the enone sul