82188-56-5

Basic information

• Product Name: methyl 2,6-dideoxy-3-O-(p-toluenesulfonyl)-α-D-arabinohexopyranoside
• Synonyms: methyl 2,6-dideoxy-3-O-(p-toluenesulfonyl)-α-D-arabinohexopyranoside
• CAS NO: 82188-56-5
• Molecular Weight: 316.375
• Mol File: 82188-56-5.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: methyl 2,6-dideoxy-3-O-(p-toluenesulfonyl)-α-D-arabinohexopyranoside(CAS DataBase Reference)
• NIST Chemistry Reference: methyl 2,6-dideoxy-3-O-(p-toluenesulfonyl)-α-D-arabinohexopyranoside(82188-56-5)
• EPA Substance Registry System: methyl 2,6-dideoxy-3-O-(p-toluenesulfonyl)-α-D-arabinohexopyranoside(82188-56-5)

Safety Data

• Hazardous Substances Data: 82188-56-5(Hazardous Substances Data)

Upstream product

• 13322-79-7 (2R,3S,4R,6S)-6-Methoxy-2-methyl-tetrahydro-pyran-3,4-diol 
• 98-59-9 p-toluenesulfonyl chloride 

Downstream Products

• 72075-75-3 (2R,3R,4R,6S)-4-Azido-6-methoxy-2-methyl-tetrahydro-pyran-3-ol 
• 72075-74-2 methyl 3-azido-2,3,6-trideoxy-α-D-arabino-hexopyranoside 
• 66409-28-7 (1R,2R,4S,6R)-4-Methoxy-2-methyl-3,7-dioxa-bicyclo[4.1.0]heptane 

Relevant articles and documents

Synthesis of thienamycin from D-glucose

Disclosed is a chiral, total synthesis of thienamycin from D-glucose which proceeds via intermediates I, II and III to known aldehyde IV which is known to be useful in the total synthesis of thienamycin (V): STR1 wherein: R is lower alkyl having 1-6 carbon atoms or bi-valent alkyl having 2-6 carbon atoms which joins the two sulfur atoms; R1 is lower alkyl or aralkyl, such as benzyl and the like; and R2 is hydrogen or a removable protecting group, such as triorganosilyl wherein the organo groups are independently selected from lower alkyl, phenyl and phenylloweralkyl.

3-Amino-4-C-carboxy-2,3,4,6-tetradeoxy-D-arabino-hexose trimethylene dithioacetal

Disclosed is a chiral, total synthesis of thienamycin from D-glucose, which proceeds via intermediates I, II, and III and joins aldehyde IV or acid V, which are known to be useful in the total synthesis of thienamycin (VI): STR1 wherein R1 is hydrogen or a removable protecting group; R is lower alkyl having 1-6 carbon atoms or bi-valent alkyl having 2-6 carbon atoms which joins the two sulfur atoms.