82268-76-6

Basic information

• Product Name: [(C₇F₈)IrCl(CO)(PCH₃(C₆H₅)2)2]
• CAS NO: 82268-76-6
• Molecular Weight: 892.188
• Mol File: 82268-76-6.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: [(C₇F₈)IrCl(CO)(PCH₃(C₆H₅)2)2](CAS DataBase Reference)
• NIST Chemistry Reference: [(C₇F₈)IrCl(CO)(PCH₃(C₆H₅)2)2](82268-76-6)
• EPA Substance Registry System: [(C₇F₈)IrCl(CO)(PCH₃(C₆H₅)2)2](82268-76-6)

Safety Data

• Hazardous Substances Data: 82268-76-6(Hazardous Substances Data)

Upstream product

• 30669-24-0 IrCl(CO)(PMePh₂)2 
• 40834-79-5 octafluoronorborna-2,5-diene 

Relevant articles and documents

REACTIONS INVOLVING TRANSITION METALS. XIX. SOME REACTIONS OF PERFLUORONORBORNADIENE WITH LOW VALENT TRANSITION METAL COMPLEXES

Perfluoronorbornadiene reacts with the compounds to give the adducts and in which one of the double bonds is coordinated to the metal atom.The platinum complex reacts further with to give 2> having both double bonds coordinated to a Pt atom.The carbonylmetal anions -> react to form the mono-substitution products (M = Mn(CO)5, Re(CO)5, Ir(CO)2(PPh3)2, Rh(CO)2(PPh3)2, but the use of an excess of - leads to substitution of one fluorine atom on each of the double bonds.The complex having M = Mn(CO)5 reacts with to afford the derivative >, and the compound where M = Ir(CO)2(PPh3)2 undergoes an oxidative addition reaction with acetyl chloride.Oxidative coupling products have been isolated on UV irradiation of a mixture of perfluoronorbornadiene and 4-CH2=CRCH=CH2)(CO)3> (R = H, Me), and under similar conditions the reaction with Fe(CO)5 affords in very low yield.