82363-84-6

Basic information

• Product Name: 1,2,4,5-Tetramethyl-3,6-bis-trimethylsilanyloxy-benzene
• Synonyms: 1,2,4,5-Tetramethyl-3,6-bis-trimethylsilanyloxy-benzene
• CAS NO: 82363-84-6
• Molecular Weight: 310.584
• Mol File: 82363-84-6.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: 1,2,4,5-Tetramethyl-3,6-bis-trimethylsilanyloxy-benzene(CAS DataBase Reference)
• NIST Chemistry Reference: 1,2,4,5-Tetramethyl-3,6-bis-trimethylsilanyloxy-benzene(82363-84-6)
• EPA Substance Registry System: 1,2,4,5-Tetramethyl-3,6-bis-trimethylsilanyloxy-benzene(82363-84-6)

Safety Data

• Hazardous Substances Data: 82363-84-6(Hazardous Substances Data)

Upstream product

• 527-17-3 Duroquinone 
• 73296-31-8 phenyltellurotrimethylsilane 
• 1450-14-2 1,1,1,2,2,2-hexamethyldisilane 
• 75-77-4 chloro-trimethyl-silane 
• 527-18-4 Durohydroquinone 

Downstream Products

• 527-17-3 Duroquinone 

Relevant articles and documents

Highly efficient and chemoselective reductive bis-silylation of quinones by silyltellurides

(matrix presented) Silyltellurides serve as new silicon-based chemoselective reducing agents and reduce quinones to the corresponding bis-silylated hydroquinones. The reaction proceeds under ambient thermal conditions without the need of any additional promoters or catalysts and gives the products in excellent yields. Several control experiments suggest that the reaction is initiated by a single electron transfer from silyltellurides to quinones.

A NEW REDUCTIVE SILYLATION OF p-QUINONES WITH HEXAMETHYLDISILANE CATALYZED BY IODINE

In the presence of a catalytic amount of iodine, hexamethyldisilane can reductively silylate p-quinones under mild conditions to afford 1,4-bis(trimethylsiloxy)arenes in high yields.