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823785-38-2

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823785-38-2 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 823785-38-2 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 8,2,3,7,8 and 5 respectively; the second part has 2 digits, 3 and 8 respectively.
Calculate Digit Verification of CAS Registry Number 823785-38:
(8*8)+(7*2)+(6*3)+(5*7)+(4*8)+(3*5)+(2*3)+(1*8)=192
192 % 10 = 2
So 823785-38-2 is a valid CAS Registry Number.

823785-38-2SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 19, 2017

Revision Date: Aug 19, 2017

1.Identification

1.1 GHS Product identifier

Product name 4-methoxy-6-phenylhex-5-ynal

1.2 Other means of identification

Product number -
Other names 5-Hexynal,4-methoxy-6-phenyl

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:823785-38-2 SDS

823785-38-2Relevant articles and documents

Rhodium-catalyzed intramolecular hydroacylation of 5- and 6-alkynals: Convenient synthesis of α-alkylidenecycloalkanones and cycloalkenones

Takeishi, Kenzo,Sugishima, Koudai,Sasaki, Kaori,Tanaka, Ken

, p. 5681 - 5688 (2007/10/03)

A novel intramolecular hydroacylation of 5- and 6-alkynals leading to α-alkylidenecycloalkanones was accomplished by using cationic a rhodium(I)/BINAP complex. For all cyclizations described, a single (E)-olefin isomer was obtained. At elevated temperature, hydroacylation and double bond migration of 5- and 6-alkynals proceeded in a one-pot reaction to give cycloalkenones. An intramolecular hydroacylation of a 7-alkynal was unsuccessful. This method represents an attractive new route to highly functionalized α-alkylidenecycloalkanones and cycloalkenones.

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