82544-59-0

Basic information

• Product Name: 1'-Cl-1,2'-(B₅H₈)(B₅H₇)
• Synonyms: 1'-Cl-1,2'-(B₅H₈)(B₅H₇)
• CAS NO: 82544-59-0
• Molecular Weight: 158.682
• Mol File: 82544-59-0.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 1'-Cl-1,2'-(B₅H₈)(B₅H₇)(CAS DataBase Reference)
• NIST Chemistry Reference: 1'-Cl-1,2'-(B₅H₈)(B₅H₇)(82544-59-0)
• EPA Substance Registry System: 1'-Cl-1,2'-(B₅H₈)(B₅H₇)(82544-59-0)

Safety Data

• Hazardous Substances Data: 82544-59-0(Hazardous Substances Data)

Upstream product

• 31831-99-9 1,2'-(B₅H₈)2 

Relevant articles and documents

Synthesis and characterization of 1-(Cl2B)B5H8 and 1-(Cl2B)-2-ClB5H7: A new boron-boron σ bond

Two new 1-(dichloroboryl)pentaborane(9) derivatives, 1-(Cl2B)B5H8 and 1-(Cl2B)-2-ClB5H7, have been produced via the reaction of BCl3 with B5H9 and 2-ClB5H8, respectively, in the presence of Friedel-Crafts catalysts. These compounds are the first examples of σ bonding between borane cluster atoms and external trigonal boron atoms. The boron-boron bonds undergo cleavage at elevated temperature in the presence of diethyl ether and insert ethylene at ambient temperature to form 1-[2-(dichloroboryl)ethyl]pentaborane(9) derivatives.