82574-98-9

Basic information

• Product Name: (E)-N,N-Dimethyl-1,5-hexadien-1-amin
• Synonyms: (E)-N,N-Dimethyl-1,5-hexadien-1-amin
• CAS NO: 82574-98-9
• Molecular Weight: 125.214
• Mol File: 82574-98-9.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (E)-N,N-Dimethyl-1,5-hexadien-1-amin(CAS DataBase Reference)
• NIST Chemistry Reference: (E)-N,N-Dimethyl-1,5-hexadien-1-amin(82574-98-9)
• EPA Substance Registry System: (E)-N,N-Dimethyl-1,5-hexadien-1-amin(82574-98-9)

Safety Data

• Hazardous Substances Data: 82574-98-9(Hazardous Substances Data)

Upstream product

• 75712-80-0 N,N-dimethylhexa-1,5-dien-3-amine 

Relevant articles and documents

Cope Rearrangements of Donor Substituted 1,5-Hexadienes

Alkoxy, alkylthio, and dialkylamino groups in position 3 of 1,5-hexadiene and in position 2 of 3,3-dimethyl-1,5-hexadiene have rather small effects on the Cope rearrangement (maximum rate acceleration by a factor of 60; maximum ΔEa = 5,5 kcal/mol = 23 kJ/mol).The pattern of substituent effects is more consistent with a diradicaloid mechanism than with a concerted sigmatropic rearrangement.