826-66-4

Basic information

• Product Name: Benzoyl fluoride, 2,4,6-trimethyl- (7CI,8CI)
• Synonyms: Benzoyl fluoride, 2,4,6-trimethyl- (7CI,8CI)
• CAS NO: 826-66-4
• Molecular Formula: C₁₀H₁₁FO
• Molecular Weight: 166.1921432
• Product Categories: ACIDHALIDE
• Mol File: 826-66-4.mol
• Article Data: 7

Chemical Properties

• Appearance: /
• CAS DataBase Reference: Benzoyl fluoride, 2,4,6-trimethyl- (7CI,8CI)(CAS DataBase Reference)
• NIST Chemistry Reference: Benzoyl fluoride, 2,4,6-trimethyl- (7CI,8CI)(826-66-4)
• EPA Substance Registry System: Benzoyl fluoride, 2,4,6-trimethyl- (7CI,8CI)(826-66-4)

Safety Data

• Hazardous Substances Data: 826-66-4(Hazardous Substances Data)

Upstream product

• 938-18-1 mesitylene-2-carboxylic acid chloride 
• 480-63-7 mesitylenecarboxylic acid 

Downstream Products

• 1402047-66-8 N-(adamantan-1-yl)-2,4,6-trimethylbenzamide 
• 141461-85-0 triisopropyl(mesitylethynyl)silane 
• 29778-31-2 1-(phenylethynyl)-2,4,6-trimethylbenzene 
• 2282-84-0 methyl 2,4,6-trimethylbenzoate 
• 104385-10-6 N-benzyl-2,4,6-trimethylbenzamide 
• 1251445-56-3 diethyl(2,4,6-trimethylbenzoyl)phosphine sulfide 

Relevant articles and documents

Acylstannanes: Cleavable and Highly Reactive Photoinitiators for Radical Photopolymerization at Wavelengths above 500 nm with Excellent Photobleaching Behavior

Within this work, a novel acylstannane-based photoinitiator (PI) is presented. Tetrakis(2,4,6-trimethylbenzoyl)stannane (1) displays outstanding properties compared to state-of-the-art acylgermane-based initiators. Most importantly, the initiator shows absorption up to 550 nm, which allows higher penetration depths, especially in highly filled photopolymers. Besides that, 1 shows extremely high photoinitiating activity towards (meth)acrylic double bonds, as well as very fast photobleaching. Furthermore, unlike many organotin compounds, 1 shows surprisingly low cytotoxicity.

CsF-Catalyzed Fluoroacylation of Tetrafluoroethylene Using Acyl Fluorides for the Synthesis of Pentafluoroethyl Ketones

A catalytic method for the synthesis of pentafluoroethyl ketones has been developed. The cesium fluoride catalyst can be used to convert acyl fluorides into the pentafluoroethyl ketones under tetrafluoroethylene pressure without generating stoichiometric

Methoxylation of Acyl Fluorides with Tris(2,4,6-trimethoxyphenyl)phosphine via C-OMe Bond Cleavage under Metal-Free Conditions

Acyl fluorides are subjected to methoxylation with tris(2,4,6-trimethoxyphenyl)phosphine (TMPP) to afford the corresponding methyl esters in good to excellent yields. This transformation is featured by C(sp2)-OMe bond cleavage under metal-free conditions. Unprecedented utilization of TMPP as a methoxylating agent realized the installation of an OMe group into the desired products.