82639-67-6

Basic information

• Product Name: 2',6'-exo-spirodioxatricyclo<5.2.1.0^2,6>decan-3'-one>
• Synonyms: 2',6'-exo-spirodioxatricyclo<5.2.1.0^2,6>decan-3'-one>
• CAS NO: 82639-67-6
• Molecular Weight: 208.257
• Mol File: 82639-67-6.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 2',6'-exo-spirodioxatricyclo<5.2.1.0^2,6>decan-3'-one>(CAS DataBase Reference)
• NIST Chemistry Reference: 2',6'-exo-spirodioxatricyclo<5.2.1.0^2,6>decan-3'-one>(82639-67-6)
• EPA Substance Registry System: 2',6'-exo-spirodioxatricyclo<5.2.1.0^2,6>decan-3'-one>(82639-67-6)

Safety Data

• Hazardous Substances Data: 82639-67-6(Hazardous Substances Data)

Upstream product

• 6118-51-0 exo-3,6-epoxy-1,2,3,6-tetrahydrophthalic anhydride 

Relevant articles and documents

Novel Synthesis of Five- and Six-Membered Spiro γ-Lactones in Rigid Bicyclic Systems

The reaction of bis(bromomagnesio)alkanes with bridged tricyclic endo- and exo-dicarboxylic anhydrides and their dihydro derivatives provides a general and versatile route to corresponding tricyclic spiro γ-butanolides.Futher extension of this methodology to the dianhydride of bicyclooctene showed appreciable regioselectivity.The subsequent transformation of spiro γ-lactones into 4-spiro-2-butenolides by retro-Diels-Alder reaction has provided a simple and convenient synthesis of these molecules.Proton and 13C NMR spectra are reported for most of the compounds.