827027-25-8Relevant articles and documents
Density, thermal expansion and viscosity of cholinium-derived ionic liquids
Costa, Anabela J.L.,Soromenho, Mario R.C.,Shimizu, Karina,Marrucho, Isabel M.,Esperanca, Jose M.S.S.,Lopes, Jose N. Canongia,Rebelo, Luis Paulo N.
, p. 1902 - 1909 (2012)
Density and viscosity data of the N-alkyl-N,N-dimethyl-N-(2-hydroxyethyl) ammonium bis(trifluoromethylsulfonyl)imide ionic liquids homologous series [N1 1 n 2(OH)][Ntf2] with n=1, 2, 3, 4 and 5 have been measured at atmospheric pressure in the 2832 group on the alkyl chain of the cation of about 17.2 cm 3mol-1, except for [N1 1 1 2(OH)]+, which exhibits an outlier behaviour. Molecular dynamics simulation results are used to explain the volumetric behaviour along the homologous series from a molecular perspective. The predictive power of group contribution methods for density and viscosity is also tested.
Structural Engineering and Optimization of Zwitterionic Salts for Expeditious Discovery of Thermoresponsive Materials
Chen, Chien-Yuan,Chen, Jin-Syuan,Chu, Yen-Ho
, (2022/01/06)
This work reported the discovery of N-triflimide (NTf)-based zwitter-ionic liquids (ZILs) that exhibit UCST-type phase transitions in water, and their further structural optimization in finetuning polarity to ultimately afford newfangled thermosensitive materials carrying attractive and biocompatible Tc values that clearly demonstrated the true value of the tunability of ZIL structure. This research established that with non-aromatic, acyclic ZILs as small-molecule thermoresponsive materials, their mixing and de-mixing with water triggered by temperatures are entirely reversible.
Cleaner enzymatic production of biodiesel with easy separation procedures triggered by a biocompatible hydrophilic ionic liquid
Chen, Qianhan,Cheng, Shuang,Fan, Dongshuang,Feng, Wanlu,Guo, Yuanyang,Li, Lingjun,Li, Zhiyong,Wang, Jianji,Zhu, Anlian
, p. 1944 - 1951 (2020/04/09)
The great challenges of modern industry and the environment make it important to develop sustainable energy resources with low cost. In this work, a cleaner enzymatic procedure for biodiesel production was developed through the utilization of a biocompatible and hydrophilic ionic liquid [Choline][H2PO4]. This ionic liquid can be synthesized from cheap raw materials through simple neutralization procedures, and it has been proved to be well biocompatible. The utilization of this ionic liquid in Novozym 435 catalyzed biodiesel production makes the reaction and work-up procedures very simple, because its hydrophilicity can lead to the implementation of a pseudo homogeneous reaction and then heterogeneous separation. Various oil resources such as triolein, sunflower oil and castor oil can all be converted to biodiesels with high yields. After the completion of reaction, both the ionic liquid and Novozym 435 can be recycled and reutilized for at least five cycles without a significant activity decrease. In addition, this reaction system can be conveniently scaled up to the multi-gram level with high efficiency and feasible separation. Overall, the above mentioned benefits make this ionic liquid based enzymatic system cleaner for the production of biodiesel and promising for further industrial applications.
ONIUM SALT HAVING ISOCYANATE GROUP AND IONIC POLYMER CONTAINING THE ONIUM SALT, AND ANTISTATIC AGENT CONTAINING THE SAME
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Paragraph 0131, (2018/10/19)
PROBLEM TO BE SOLVED: To provide a new onium salt which can impart antistatic properties to a resin and an ionic polymer having a structure of the onium salt as a partial skeleton, and an antistatic agent containing the ionic polymer, and to provide an antistatic agent which shows less lowering of antistatic properties even by water immersion treatment and a resin composition. SOLUTION: There are provided onium salt represented by formula (1); an ionic polymer obtained by reaction of an acrylic polymer having a hydroxyl group and the onium salt represented by formula (1); and an antistatic agent containing the ionic polymer. In formula (1), L represents an alkylene group which may have a substituent or an arylene group which may have a substituent; A- represents anion which has a fluorine atom; B+ represents ammonium cation, pyridinium cation, imidazolium cation or phosphonium cation; and D represents O, NH or S. SELECTED DRAWING: None COPYRIGHT: (C)2018,JPOandINPIT