82725-27-7

Basic information

• Product Name: 2-Benzyloxythioformanilid
• CAS NO: 82725-27-7
• Molecular Weight: 243.329
• Mol File: 82725-27-7.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 2-Benzyloxythioformanilid(CAS DataBase Reference)
• NIST Chemistry Reference: 2-Benzyloxythioformanilid(82725-27-7)
• EPA Substance Registry System: 2-Benzyloxythioformanilid(82725-27-7)

Safety Data

• Hazardous Substances Data: 82725-27-7(Hazardous Substances Data)

Upstream product

• 20012-63-9 o-(benzyloxy)aniline 
• 29392-46-9 ethyl thioformate 

Downstream Products

• 82725-42-6 1-(2-Benzyloxyphenyl)-4-methylthio-2-azetidinon 
• 81215-35-2 1-(2-Hydroxyphenyl)-4-methylthio-2-azetidinon 
• 82725-38-0 N-(2-benzyloxyphenyl)formamide 

Relevant articles and documents

Synthesis of 1-Aryl-4-methylthio-2-azetidinones

The N-arylthioformimidates 4a-e, which may be obtained by S-alkylation of the thioformanilides 3a-e, react with chloroacetylchloride/triethylamine to yield the (3R,4S/3S,4R)-1-aryl-3-chloro-4-methylthio-2-azetidinones 5a-e and the formanilides 6a-e.Dehalogenation of 5b-e with tri-n-butyltinhydride yield the title compounds 7b-e.Hydrogenolysis of 7b and 7c yields 7f and 7g. - Keywords: 1-Aryl-3-chloro-4-methylthio-2-azetidinones; 1-Aryl-4-methylthio-2-azetidinones; Dehalogenation; N-Arylthioformimidates; Tri-n-butyltinhydride