827307-99-3Relevant articles and documents
Cis- and trans-N-(Benzylsulfinyl)hexahydrobenzoxazolidin-2-ones as novel chiral sulfinyl transfer reagents
Clara-Sosa, Angel,Pérez, Lydia,Sánchez, Mario,Melgar-Fernández, Roberto,Juaristi, Eusebio,Quintero, Leticia,Anaya De Parrodi, Cecilia
, p. 12147 - 12152 (2007/10/03)
The synthesis of N-benzylsulfinyl derivatives 5a-d from both pairs of enantiomeric hexahydrobenzoxazolidin-2-ones 4a-d is reported. The use of 5a-d as effective chiral sulfinylating reagents in the preparation of enantiopure sulfoxides (e.e.>98%) is also reported. Graphical Abstract
