82736-62-7

Basic information

• Product Name: 3H-Diazirine, 3-methoxy-3-phenyl-
• CAS NO: 82736-62-7
• Molecular Formula: C8H8N2O
• Molecular Weight: 148.164
• Mol File: 82736-62-7.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: 3H-Diazirine, 3-methoxy-3-phenyl-(CAS DataBase Reference)
• NIST Chemistry Reference: 3H-Diazirine, 3-methoxy-3-phenyl-(82736-62-7)
• EPA Substance Registry System: 3H-Diazirine, 3-methoxy-3-phenyl-(82736-62-7)

Safety Data

• Hazardous Substances Data: 82736-62-7(Hazardous Substances Data)

Upstream product

• 124-41-4 sodium methylate 
• 4222-25-7 3-bromo-3-phenyl-3H-diazirine 

Downstream Products

• 37823-96-4 pentacarbonyl(methoxyphenylmethylene)tungsten⁽⁰⁾ 
• 27436-93-7 pentacarbonyl(1-methoxybenzylidene)chromium⁽⁰⁾ 
• 82736-63-8 1-methoxy-1-phenyl-2,2-dimethylcyclopropane 
• 118964-98-0 1-methoxy-2,2,3,3-tetramethyl-1-phenylcyclopropane 
• 780810-43-7 1-methoxy-1-phenyl-2-carbomethoxycyclopropane 
• 344304-35-4 1-methoxy-1-phenyl-2-cyanocyclopropane 
• 59526-67-9 methoxyphenylcarbene 
• 93-58-3 benzoic acid methyl ester 
• 1155-16-4 C₁₆H₁₆N₂O₂ 
• 100-52-7 benzaldehyde 
• 2236-57-9 Benzaldehyde ethyl methyl acetal 
• 118964-99-1 [Methoxy-(1,1,2-trimethyl-allyloxy)-methyl]-benzene 
• 118965-00-7 [Methoxy-(1,1,2-trimethyl-allylperoxy)-methyl]-benzene 
• 82736-65-0 (1-Methoxy-2,2,3-trimethyl-but-3-enyl)-benzene 

Relevant articles and documents

Methoxyphenyldiazirine as Precursor to Methoxyphenylcarbene

Reaction of bromo(phenyl)diazirine (2) with methoxide ion gives methoxy(phenyl)diazirine (3), which yields cyclopropanes (4) on photolysis in alkenes.

Absolute Rate and Philicity Studies of Methoxyphenylcarbene. An Extended Range for Carbenic Ambiphilicity

Methoxyphenylcarbene (MeOCPh) was generated by photolysis (-10 deg C) or thermolysis (25, 45 deg C) of 3-methoxy-3-phenyldiazirine and added to six alkenes, affording the corresponding cyclopropanes.The substrates and their relative reactivities toward th