82769-14-0

Basic information

• Product Name: ethyl trans-3-methyl-1-oxirane-2-carboxylate
• Synonyms: ethyl trans-3-methyl-1-oxirane-2-carboxylate
• CAS NO: 82769-14-0
• Molecular Weight: 130.144
• Mol File: 82769-14-0.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: ethyl trans-3-methyl-1-oxirane-2-carboxylate(CAS DataBase Reference)
• NIST Chemistry Reference: ethyl trans-3-methyl-1-oxirane-2-carboxylate(82769-14-0)
• EPA Substance Registry System: ethyl trans-3-methyl-1-oxirane-2-carboxylate(82769-14-0)

Safety Data

• Hazardous Substances Data: 82769-14-0(Hazardous Substances Data)

Upstream product

• 89490-41-5 (S)-2-Chloro-3-hydroxy-butyric acid ethyl ester 
• 609-15-4 ethyl 2-chloro-3-oxo-butyrate 
• 113791-25-6 1,3-bis<(trimethylsilyl)oxy>-1-ethoxy-butene 
• 623-73-4 diazoacetic acid ethyl ester 
• 75-07-0 acetaldehyde 
• 136805-79-3 ethyl 2-<(p-nitrobenzenesulfonyl)oxy>-3-hydroxybutanoate 
• 136805-79-3 ethyl 2-<(p-nitrobenzenesulfonyl)oxy>-3-hydroxybutanoate 
• 124716-79-6 Ethyl 2-<<(p-nitrophenyl)sulfonyl>oxy>acetoacetate 

Downstream Products

• 10133-06-9 methyl (+/-)-trans-(2,3)-epoxy butanoate 
• 107686-02-2 (2R,3S)-2-Hydroxy-3-methoxy-butyric acid ethyl ester 
• 107686-00-0 (2S,3S)-2-Hydroxy-3-phenylsulfanyl-butyric acid ethyl ester 
• 107685-97-2 4-ethoxy-3-hydroxy-4-oxobutan-2-yl benzoate 
• 107685-99-4 (2S,3R)-3-Benzyloxy-2-hydroxy-butyric acid ethyl ester 
• 107685-98-3 (2R,3S)-2-Hydroxy-3-phenoxy-butyric acid ethyl ester 
• 15933-07-0 Ethyl 2-oxobutanoate 

Relevant articles and documents

The synthesis of solvent-free glycidic esters from diazoesters and carbonyl compounds catalysed by lanthanide trifiates

The results of the reaction between ethyl diazoacetate and carbonyl compounds catalysed by lanthanide triflates are described. Aldehydes, and α-unsubstituted and α-monosubstituted cyclohexanones react to give the selective formation of α,β-epoxy esters (g

Synthesis and Reactions of 3-Hydroxy-2-nosyloxy Esters Produced by the Stereoselective Reduction of 2-Nosyloxy-3-keto Esters

The reduction of 2-nosyloxy-3-keto esters is an effective method for the preparation of 3-hydroxy-2-nosyloxy esters.The reduction is stereoselective for the syn isomer.The anti isomer can be produced as the major product by the addition of p-nitrobenzenesulfonyl peroxide to ketene bis-silyl acetal derivatives of 3-hydroxy esters.The diastereomers are separable chromatographically and can be converted stereospecifically to glycidic esters and 2-azido-3-hydroxy esters.As such they appear to have excellent potential as versatile synthetic intermediates for the synthesis of 1,2,3-trifunctional substances.