82832-29-9Relevant articles and documents
Iron-catalysed fluoroaromatic coupling reactions under catalytic modulation with 1,2-bis(diphenylphosphino)benzene
Hatakeyama, Takuji,Kondo, Yoshiyuki,Fujiwara, Yu-Ichi,Takaya, Hikaru,Ito, Shingo,Nakamura, Eiichi,Nakamura, Masaharu
supporting information; experimental part, p. 1216 - 1218 (2009/07/10)
A catalytic amount of 1,2-bis(diphenylphosphino)benzene (DPPBz) achieves selective cleavage of sp3-carbon-halogen bond in the iron-catalysed cross-coupling between polyfluorinated arylzinc reagents and alkyl halides, which was unachievable with
Reduction of 3-Substituted 1-Arylcyclobutanols
Kinnius, Joerg,Dehmlow, Eckehard Volker
, p. 421 - 423 (2007/10/03)
A useful and specific method for the the title reaction (1 → 2) involves treatment with NaBH4 in CF3COOH whereas other procedures from the literature yield hard-to-separate mixtures. 1-Arylcyclohexanols 3 give mainly cyclohexenes with borohydride/trifluoroacetic acid. Their reduction to compounds 4 ,however, is possible with MeSO3H/ NaBH4.