82845-98-5

Basic information

• Product Name: 1-<3,5-bis-O-(tert-butyldimethylsilyl)-β-D-arabinofuranosyl>-uracil
• CAS NO: 82845-98-5
• Molecular Weight: 472.729
• Mol File: 82845-98-5.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 1-<3,5-bis-O-(tert-butyldimethylsilyl)-β-D-arabinofuranosyl>-uracil(CAS DataBase Reference)
• NIST Chemistry Reference: 1-<3,5-bis-O-(tert-butyldimethylsilyl)-β-D-arabinofuranosyl>-uracil(82845-98-5)
• EPA Substance Registry System: 1-<3,5-bis-O-(tert-butyldimethylsilyl)-β-D-arabinofuranosyl>-uracil(82845-98-5)

Safety Data

• Hazardous Substances Data: 82845-98-5(Hazardous Substances Data)

Upstream product

• 55264-11-4 (2R,3R,3aS,9aR)-3-((tert-butyldimethylsilyl)oxy)-2-(((tert-butyldimethylsilyl)oxy)methyl)-3,3a-dihydro-2H-furo[2',3':4,5]oxazolo[3,2-a]pyrimidin-6(9aH)-one 
• 1666-13-3 diphenyl diselenide 

Relevant articles and documents

Selenoxide Elimination for the Synthesis of Unsaturated-Sugar Uracil Nucleosides

Introduction of a phenylseleno group to the sugar portion of uracil nucleosides and selenoxide elimination reactions of the resulting selenium-containing derivatives are described.A phenylselenide anion prepared by reducing (PhSe)2 with LiAlH4 was found to be highly reactive.By using this selenide as a nucleophile, ring openings of various types of cyclonucleosides and nucleosides having an anhydro structure in the sugar portion were accomplished.The products, which contain a phenylseleno group in the sugar portion, were oxidized with m-CPBA in CH2Cl2, and their susceptibility to the selenoxide elimination and regiochemistry of the reaction was investigated.