83020-75-1

Basic information

• Product Name: oxophorone trimethylsilylenol ether
• Synonyms: oxophorone trimethylsilylenol ether
• CAS NO: 83020-75-1
• Molecular Weight: 224.375
• Mol File: 83020-75-1.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: oxophorone trimethylsilylenol ether(CAS DataBase Reference)
• NIST Chemistry Reference: oxophorone trimethylsilylenol ether(83020-75-1)
• EPA Substance Registry System: oxophorone trimethylsilylenol ether(83020-75-1)

Safety Data

• Hazardous Substances Data: 83020-75-1(Hazardous Substances Data)

Upstream product

• 16029-98-4 trimethylsilyl iodide 
• 1125-21-9 2,6,6-trimethyl-2-cyclohexene-1,4-dione 
• 27607-77-8 trimethylsilyl trifluoromethanesulfonate 
• 75-77-4 chloro-trimethyl-silane 

Downstream Products

• 83020-76-2 (3'E)-4-hydroxy-4-(5'-hydroxy-3'-methyl-3'-penten-1'-inyl)-3,5,5-trimethyl-2-cyclohexen-1-on 

Relevant articles and documents

Double Michael addition reaction of oxophorone and its derivatives leading to bicyclo[2.2.2]octane Compounds

Trimethylsilylenol ethers of oxophorone 1 and its derivatives provided bicyclo[2.2.2]octane compounds 5 in a selective way.

An expedient access to highly functionalized B-seco taxoid frameworks

We report a convergent approach which proceeds in the A+C→A C direction and leads in a straightforward manner to the conveniently functionalized B- seco-taxane frameworks 7 and 8, offering linkage possibilities at C1-C2.