830345-45-4

Basic information

• Product Name: Benzene, 1,1'-(2,2-dimethyl-1-methylene-1,3-propanediyl)bis-
• CAS NO: 830345-45-4
• Molecular Formula: C18H20
• Molecular Weight: 236.357
• Mol File: 830345-45-4.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Benzene, 1,1'-(2,2-dimethyl-1-methylene-1,3-propanediyl)bis-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, 1,1'-(2,2-dimethyl-1-methylene-1,3-propanediyl)bis-(830345-45-4)
• EPA Substance Registry System: Benzene, 1,1'-(2,2-dimethyl-1-methylene-1,3-propanediyl)bis-(830345-45-4)

Safety Data

• Hazardous Substances Data: 830345-45-4(Hazardous Substances Data)

Upstream product

• 13031-08-8 4-phenylpivalophenone 
• 1779-49-3 Methyltriphenylphosphonium bromide 

Downstream Products

• 98-86-2 acetophenone 
• 100-86-7 2-Methyl-1-phenyl-2-propanol 
• 1944-83-8 2-methyl-1-phenyl-2-propylhydroperoxide 

Relevant articles and documents

Synthesis of cyclic peroxides by chemo- and regioselective peroxidation of dienes with Co(II)/O2/Et3SiH

(Chemical Equation Presented). In the competitive peroxidation of mixtures of two alkenes with Co(II)/O2/Et3SiH, it was found that the relative reactivities of the alkene substrates are influenced by three major factors:. (1) relative stability of the intermediate carbon-centered radical formed by the reaction of the alkene with HCo(III) complex, (2) steric effects around the C=C double bond, and (3) electronic factors associated with the C=C double bond. Consistent with results from simple alkenes, the chemo-and regioselective peroxidation of dienes was also realized. Depending on the diene structure, the product included not only the expected acyclic unsaturated triethylsilyl peroxides but also 1,2-dioxolane and 1,2-dioxane derivatives via intramolecular cyclization of the unsaturated peroxy radical intermediates.