83074-92-4

Basic information

• Product Name: 3-(p-Tolylsulfinyl)-2-butan-2-on
• Synonyms: 3-(p-Tolylsulfinyl)-2-butan-2-on
• CAS NO: 83074-92-4
• Molecular Weight: 210.297
• Mol File: 83074-92-4.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: 3-(p-Tolylsulfinyl)-2-butan-2-on(CAS DataBase Reference)
• NIST Chemistry Reference: 3-(p-Tolylsulfinyl)-2-butan-2-on(83074-92-4)
• EPA Substance Registry System: 3-(p-Tolylsulfinyl)-2-butan-2-on(83074-92-4)

Safety Data

• Hazardous Substances Data: 83074-92-4(Hazardous Substances Data)

Upstream product

• 1519-39-7 (R)-methyl p-tolyl sulfoxide 
• 66536-78-5 (+)-(R)-1-(p-tolylsulfinyl)-2-propanone 
• 74-88-4 methyl iodide 
• 106-45-6 para-thiocresol 
• 933-00-6 p-methylbenzenesulfenyl chloride 
• 54091-17-7 3-(p-tolylthio)butan-2-one 
• 61783-72-0 (1-Methyl-1,2-propadienyl)(p-tolyl)sulfoxid 

Downstream Products

• 142184-57-4 (2R,3R,R_S)-3-(p-tolylsulfinyl)butan-2-ol 
• 142075-98-7 (2R,3S,R_S)-3-(p-tolylsulfinyl)butan-2-ol 
• 144694-76-8 (S₂,S₃,R_S)-2-hydroxy-2-methyl-3-<(4-methylphenyl)sulfinyl>butanenitrile 
• 144694-76-8 (S₂,R₃,R_S)-2-hydroxy-2-methyl-3-<(4-methylphenyl)sulfinyl>butanenitrile 
• 78-93-3 butanone 
• 137033-11-5 tert-Butyl-dimethyl-[1-methylene-2-(toluene-4-sulfinyl)-allyloxy]-silane 
• 137033-05-7 3-(p-tolylthio)-2-(trimethylsilyloxy)-1,3-butadiene 

Relevant articles and documents

1,3-Asymmetric Induction in the Reduction of α-Alkyl β-Ketosulfoxides with DIBAL/ZnBr2

The highly stereoselective reduction of chiral α-alkyl β-ketosulfoxides with DIBAL/ZnBr2 is governed by the configuration at the sulfur (1,3-induction) and not by that of the C-α (1,2-induction) as it has been previously reported.This fact considerably in

Phosphorus- and Sulfur-substituted Allenes in Synthesis, III. - β-Keto Sulfoxides from 3-Alkyn-1-ols via Allenic Sulfoxides

Allenic sulfoxides 3, readily available by sigmatropic rearrangement of sulfenic esters 2 of 3-alkyn-1-ols 1, can be transformed to give β-keto sulfoxides 9 by nucleophilic addition of diethylamine and subsequent hydrolysis of the formed enamines.