831192-69-9

Basic information

• Product Name: (1S,R_S)-N-tert-butanesulfinyl-1-phenylbut-3-en-1-amine
• Synonyms: (1S,R_S)-N-tert-butanesulfinyl-1-phenylbut-3-en-1-amine
• CAS NO: 831192-69-9
• Molecular Weight: 251.393
• Mol File: 831192-69-9.mol
• Article Data: 13

Chemical Properties

• CAS DataBase Reference: (1S,R_S)-N-tert-butanesulfinyl-1-phenylbut-3-en-1-amine(CAS DataBase Reference)
• NIST Chemistry Reference: (1S,R_S)-N-tert-butanesulfinyl-1-phenylbut-3-en-1-amine(831192-69-9)
• EPA Substance Registry System: (1S,R_S)-N-tert-butanesulfinyl-1-phenylbut-3-en-1-amine(831192-69-9)

Safety Data

• Hazardous Substances Data: 831192-69-9(Hazardous Substances Data)

Upstream product

• 186249-76-3 (R,E)-2-methyl-N-(phenylmethylene)-2-propanesulfinamide 
• 627-15-6 1,3-dibromopropene 
• 196929-85-8 (R)-N-benzylidene-2-methylpropane-2-sulfinamide 
• 688-61-9 Triallylborane 
• 1730-25-2 allylmagnesium bromide 
• 72824-04-5 2-Allyl-4,4,5,5-tetramethyl-1,3,2-dioxaborolane 
• 100-52-7 benzaldehyde 
• 107-18-6 allyl alcohol 
• 1208066-51-6 (R_S,S)-N-(1-(phenyl)but-3-yn-1-yl)-2-methylpropane-2-sulfinamide 
• 106-95-6 allyl bromide 

Downstream Products

• 1190958-62-3 (2R,2'S)-N-tert-butylsulfonyl-2-(2-amino-2-phenylethyl)oxirane 
• 1190958-64-5 (2S,2'S)-N-tert-butylsulfonyl-2-(2-amino-2-phenylethyl)oxirane 
• 130887-64-8 (S)-1-phenylbut-3-en-1-amine hydrochloride 

Relevant articles and documents

Homoallylic amines as efficient chiral inducing frameworks in the conjugate addition of amides to α,β-unsaturated esters. An entry to enantio-enriched diversely substituted amines

The diastereoselective conjugate addition of secondary homoallylamines, obtained in the enantioenriched form via allylmetallation of imines, to α,β-unsaturated esters is reported. This method allows access to valuable building blocks as well as heterocyclic skeletons, providing tertiary amines bearing two chains integrating a stereogenic center adjacent to the nitrogen atom.

Adducts of Triallylborane with Ammonia and Aliphatic Amines as Stoichiometric Allylating Agents for Aminoallylation Reaction of Carbonyl Compounds

Triallylborane-amines adducts are effective stoichiometric allylating agents in the aminoallylation reaction of carbonyl compounds in methanol. Moreover, copper-catalyzed diastereoselective allylation of Ellman's imine was achieved with triallylborane-methylamine adduct.

2,2- and 2,6-diarylpiperidines by aryl migration within lithiated urea derivatives of tetrahydropyridines

2-Aryltetrahydropyridines formed by anionic cyclization or ring-closing metathesis were converted to their N′-aryl urea derivatives. Depending on the position of the unsaturation within the tetrahydropyridine ring, metalation by deprotonative lithiation or carbolithiation led to migration of the N′-aryl substituent to the 2- or 6-position via intramolecular nucleophilic attack of a benzylic organolithium on the aryl ring. The products are a range of 2,2-, 2,2,3-, and 2,6-polysubstituted piperidine derivatives. Related chemistry was observed in pyrroline homologues.