83125-89-7

Basic information

• Product Name: N-phenyl-N-(tosyloxy)benzamide
• Synonyms: N-phenyl-N-(tosyloxy)benzamide
• CAS NO: 83125-89-7
• Molecular Weight: 367.425
• Mol File: 83125-89-7.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: N-phenyl-N-(tosyloxy)benzamide(CAS DataBase Reference)
• NIST Chemistry Reference: N-phenyl-N-(tosyloxy)benzamide(83125-89-7)
• EPA Substance Registry System: N-phenyl-N-(tosyloxy)benzamide(83125-89-7)

Safety Data

• Hazardous Substances Data: 83125-89-7(Hazardous Substances Data)

Upstream product

• 100-65-2 N-Phenylhydroxylamine 
• 98-88-4 benzoyl chloride 
• 304-88-1 N-phenylbenzohydroxamic acid 
• 98-59-9 p-toluenesulfonyl chloride 

Downstream Products

• 104-15-4 toluene-4-sulfonic acid 
• 3743-70-2 N-(2-hydroxyphenyl)benzamide 
• 49834-35-7 N-<2-(4-Methylphenylsulfonyloxy)phenyl>benzamid 
• 5395-00-6 N-(2-methoxyphenyl)benzamide 
• 7472-54-0 N-(p-methoxyphenyl)benzamide 

Relevant articles and documents

Photoacid generators (PAGs) based on N-acyl-N-phenylhydroxylamines for carboxylic and sulfonic acids

Simple and efficient photoacid generators (PAGs) for carboxylic and sulfonic acids based on N-acyl-N-phenylhydroxylamines have been demonstrated. Irradiation of o-carboxylates and thermally rearranged o-arenesulfonates of N-acyl-N-phenylhydroxylamines using UV light (≥254 nm) in aqueous methanolic solution resulted in efficient generation of carboxylic and sulfonic acids, respectively. The carboxylic acid generation ability of N-acyl-N- phenylhydroxylamines was found to be dependent on their N-acyl substituents. Further, polymer bearing o-arenesulfonates of N-acyl-N-phenylhydroxylamine was synthesized and demonstrated as PAG for sulfonic acids.