83225-58-5Relevant articles and documents
REACTION OF HYDROXY AND CARBONYL COMPOUNDS WITH SULFUR TETRAFLUORIDE. VIII. THE REACTIONS OF ALIPHATIC α-DIKETONES WITH SF4
Burmakov, A. I.,Stepanov, I. V.,Kunshenko, B. V.,Sedova, L. N.,Alekseeva, L. A.,Yagupol'skii, L. M.
, p. 1009 - 1013 (2007/10/02)
Aliphatic α-diketones react with sulfur tetrafluoride in anhydrous hydrogen fluoride to give the corresponding tetrafluoroalkanes.In addition to 2,2,3,3-tetrafluorobutane, the reaction of butanedione with SF4 in the presence of catalytic amounts of HF yields 2,3-difluorobutyleneglycol-2,3-orthosulfite and fluoro-substituted ethers.Butanedione homologs yield tetrafluoro derivatives and fluoroolefins.
