83266-40-4

Basic information

• Product Name: 1-Propanone, 3-[(3-methylphenyl)amino]-1-phenyl-
• CAS NO: 83266-40-4
• Molecular Formula: C16H17NO
• Molecular Weight: 239.317
• Mol File: 83266-40-4.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: 1-Propanone, 3-[(3-methylphenyl)amino]-1-phenyl-(CAS DataBase Reference)
• NIST Chemistry Reference: 1-Propanone, 3-[(3-methylphenyl)amino]-1-phenyl-(83266-40-4)
• EPA Substance Registry System: 1-Propanone, 3-[(3-methylphenyl)amino]-1-phenyl-(83266-40-4)

Safety Data

• Hazardous Substances Data: 83266-40-4(Hazardous Substances Data)

Upstream product

• 71-43-2 benzene 
• 936-59-4 3-chloropropiophenone 
• 108-44-1 1-amino-3-methylbenzene 
• 879-72-1 3-(dimethylamino)propiophenone hydrochloride 

Downstream Products

• 1048974-53-3 1-phenyl-3-(3-methylphenyl)-6-phenyl-3,4-dihydropyrimidin-2(1H)-one 
• 78994-04-4 2-Chloro-6-phenyl-3-m-tolyl-3,4-dihydro-[1,3,2]oxazaphosphinine 2-oxide 

Relevant articles and documents

I2-Promoted Intramolecular Oxidative Cyclization of Butenyl Anilines: A Facile Route to Benzo[b]azepines

A metal-free approach for the synthesis of seven-membered N-heterocycles has been developed by the I2-promoted intramolecular cross-coupling/annulation of butenyl anilines. This cyclization reaction involves C?H activation and C?C bond formation and exhibits good functional group tolerance. A series of benzo[b]azepine derivatives are obtained in moderate to good yields.

A convenient synthesis of novel 1,3,4-triaryl-3,4-dihydropyrimidin-2(1H)- ones by cyclization of aromatic isocyanates with β-arylamino-1- phenylpropan-1-ones

(Chemical Equation Presented) A simple one-step method for preparation of novel 1,3,4-triaryl-3,4-dihydropyrimidin-2(1H)-ones has been developed by reaction of aromatic isocyanates with β-arylamino-1-phenylpropan-1-ones in refluxing toluene in the presence of KHSO4 and HCl.

Synthesis and Reactions of 3,6-Diaryl-3,4-dihydro-1,3,2-oxazaphosphorin-2-oxides

Aryl β-arylaminoethyl ketones (1), when reacted with phosphorus oxychloride followed by treatment with triethylamine, afford 3,6-diaryl-2-chloro-3,4-dihydro-1,3,2-oxazaphosphorin-2-oxides (3a-u), a hitherto unreported ring system.The oxazaphosphorin (3q), viz. 2-chloro-3-m-anisyl-6-phenyl-3,4-dihydro-1,3,2-oxazaphosphorin, is converted into 7-methoxy-4-phenylquinoline on keeping.This transformation is specific to 3q since other oxazaphosphorins fail to give the quinoline derivative.