83458-92-8

Basic information

• Product Name: ((2S,3S)-3-(3-(benzyloxy)propyl)oxiran-2-yl)methanol
• Synonyms: ((2S,3S)-3-(3-(benzyloxy)propyl)oxiran-2-yl)methanol
• CAS NO: 83458-92-8
• Molecular Weight: 222.284
• Mol File: 83458-92-8.mol
• Article Data: 11

Chemical Properties

• CAS DataBase Reference: ((2S,3S)-3-(3-(benzyloxy)propyl)oxiran-2-yl)methanol(CAS DataBase Reference)
• NIST Chemistry Reference: ((2S,3S)-3-(3-(benzyloxy)propyl)oxiran-2-yl)methanol(83458-92-8)
• EPA Substance Registry System: ((2S,3S)-3-(3-(benzyloxy)propyl)oxiran-2-yl)methanol(83458-92-8)

Safety Data

• Hazardous Substances Data: 83458-92-8(Hazardous Substances Data)

Upstream product

• 133407-67-7 ethyl (E)-6-(benzyloxy)hex-2-enoate 
• 100-39-0 benzyl bromide 
• 5470-84-8 4-benzyloxybutanal 
• 4541-14-4 4-benzyloxy-butan-1-ol 
• 100571-53-7 6-(benzyloxy)hex-2-yn-1-ol 
• 5375-00-8 3-benzyloxypropyl iodide 
• 83458-91-7 (2E)-6-(benzyloxy)hex-2-en-1-ol 
• 288580-72-3 ethyl 6-benzyloxy-2-hexenoate 
• 81518-74-3 1-benzyloxy-4-pentene 
• 13038-15-8 (E)-6-hydroxy-hex-2-enoic acid ethyl ester 

Downstream Products

• 921207-68-3 ethyl (E)-(5S)-8-(benzyloxy)-5-hydroxy-2-octenoate 
• 921207-65-0 ethyl 2-{(2S,4S,6S)-6-[3-(benzyloxy)propyl]-2-phenyl-1,3-dioxan-4-yl}acetate 
• 902128-51-2 (2R,3S)-6-Benzyloxy-hexane-1,2,3-triol 
• 902128-52-3 2,2-Dimethyl-propionic acid (2R,3S)-6-benzyloxy-2,3-dihydroxy-hexyl ester 
• 902128-53-4 ((4R,5S)-5-(3-(benzyloxy)propyl)-2,2-dimethyl-1,3-dioxolan-4-yl)methyl pivalate 
• 1293373-04-2 C₁₃H₁₇IO₂ 
• 1195757-50-6 C₁₉H₃₄O₂Si 

Relevant articles and documents

Stereoselective synthesis of dendrodolide-L

An efficient stereoselective total synthesis of 12-membered macrolide dendrodolide L has been achieved. The key reactions involved are Keck asymmetric allylation, Jacobsen's hydrolytic kinetic resolution, Sharpless asymmetric epoxidation, Mitsunobu reaction and ring-closing metathesis reaction.

The stereoselective total synthesis of (+)-stagonolide B

The stereoselective total synthesis of the nonenolide, (+)-stagonolide B is described. The key steps involve epoxide homologation, hydrolytic kinetic resolution and ring-closing metathesis.

Stereoselective synthesis of a key intermediate of (-)-apicularen A

Progress towards the stereoselective formal synthesis of (-)-apicularen A is described. The convergent approach involves the assembly of aliphatic and aromatic fragments via Grubbs's cross metathesis. Other key reactions in the strategy include Sharpless