83577-50-8

Basic information

• Product Name: methyl 5-phenyl-3-pyrrolidinopenta-2E,4E-dienoate
• Synonyms: methyl 5-phenyl-3-pyrrolidinopenta-2E,4E-dienoate
• CAS NO: 83577-50-8
• Molecular Weight: 257.332
• Mol File: 83577-50-8.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: methyl 5-phenyl-3-pyrrolidinopenta-2E,4E-dienoate(CAS DataBase Reference)
• NIST Chemistry Reference: methyl 5-phenyl-3-pyrrolidinopenta-2E,4E-dienoate(83577-50-8)
• EPA Substance Registry System: methyl 5-phenyl-3-pyrrolidinopenta-2E,4E-dienoate(83577-50-8)

Safety Data

• Hazardous Substances Data: 83577-50-8(Hazardous Substances Data)

Upstream product

• 83577-47-3 methyl 4-(trimethylsilyl)-3-pyrrolidinocrotonate 
• 100-52-7 benzaldehyde 
• 55212-79-8 (E)-3-pyrrolidinobut-2-enoic acid methyl ester 
• 90087-77-7 methyl 3-pyrrolidinoacrylate 

Relevant articles and documents

Chemistry of 4-trimethylsilyl-3-dialkylaminocrotonate esters and the cycloaromatization reactions with enamines

Methyl 4-trimethylsilyl-3-dialkylaminocrotonate is synthesized by the silylation of methyl 3-dialkylaminocrotonate.It reacts with carbonyl electrophiles at its γ-position.The unusual regiochemistry of this reaction is studied and rationalized.It reacts with enamines derived from acyclic ketones to give aromatic compounds in a 3C+3C combination and with enamines derived from cycloketones of 5- to 8-membered rings to give aromatic compounds in a 4C+2C combination.A mechanism for this cycloaromatization reaction is proposed.