83759-18-6Relevant articles and documents
Control of Regioselectivity in the Addition of Sulphenyl Chlorides to 3,3-Dimethylbutyne (t-Butylacetylene) as a Method for Differential Functionalization of Triple Bonds
Capozzi, Giuseppe,Caristi, Corrado,Lucchini, Vittorio,Modena, Giorgio
, p. 2197 - 2202 (2007/10/02)
Methanesulphenyl chloride and toluene-p-sulphenyl chloride react with 3,3-dimethylbutyne to give regio- and stereo-specifically (E)-1-chloro-3,3-dimethyl-2-methylthiobut-1-ene (3a) and (E)-1-chloro-3,3-dimethyl-2-p-tolylthiobut-1-ene (3b). trans-cis-Acid-