83999-44-4

Basic information

• Product Name: 2,6,6-trimethyl-1-trimethylsilyloxycyclohexene
• Synonyms: 2,6,6-trimethyl-1-trimethylsilyloxycyclohexene
• CAS NO: 83999-44-4
• Molecular Weight: 212.407
• Mol File: 83999-44-4.mol
• Article Data: 6

Chemical Properties

• CAS DataBase Reference: 2,6,6-trimethyl-1-trimethylsilyloxycyclohexene(CAS DataBase Reference)
• NIST Chemistry Reference: 2,6,6-trimethyl-1-trimethylsilyloxycyclohexene(83999-44-4)
• EPA Substance Registry System: 2,6,6-trimethyl-1-trimethylsilyloxycyclohexene(83999-44-4)

Safety Data

• Hazardous Substances Data: 83999-44-4(Hazardous Substances Data)

Upstream product

• 75-77-4 chloro-trimethyl-silane 
• 2408-37-9 2,2,6-trimethylcyclohexan-1-one 
• 27607-77-8 trimethylsilyl trifluoromethanesulfonate 

Downstream Products

• 80994-25-8 <6-D>-2,2,6-Trimethylcyclohexanone 
• 130921-05-0 (Dimethoxy-phosphoryl)-acetic acid 1,3,3-trimethyl-2-oxo-cyclohexyl ester 
• 15356-74-8 (+/-)-dihydroactinidiolide 
• 16797-54-9 2-Acetoxy-2,6,6-trimethylcyclohexanone 
• 20013-73-4 2,6,6-trimethylcyclohex-2-en-1-one 
• 73751-62-9 1,3,3-trimethyl-2-oxo-cyclohexanecarboxylic acid methyl ester 
• 53326-69-5 2,2,6-Trimethyl-6-(3-oxo-butyl)-cyclohexanone 
• 136587-31-0 (2RS)-2-<(RS)-3-furylhydroxymethyl>-2,6,6-trimethylcyclohexanone 
• 106033-56-1 (R)-2,2,6-trimethyl-cyclohexanone 
• 106036-02-6 (S)-2,2,6-trimethyl-cyclohexanone 
• 2816-63-9 2-bromo-2,6,6-trimethylcyclohexanone 

Relevant articles and documents

Organocatalytic enantioselective protonation of silyl enolates mediated by cinchona alkaloids and a latent source of HF

Hidden benefits: The enantioselective organocatalytic protonation of silyl enolates has been achieved by using readily available cinchona alkaloid catalysts (1) and a latent source of HF that delivers "at will" the active catalytic hydrogen fluoride salt

ENANTIOSELECTIVE DEPROTONATION OF TWO RACEMIC CYCLIC CARBONYL COMPOUNDS BY A CHIRAL LITHIUM AMIDE

The cyclic carbonyl compounds 2 and 8 have been obtained in optical active form (o.y. 46percent and 36percent, respectively) from the racemic compounds by a deprotonation/protonation sequence, using chiral lithium amide 1.The optical activity of 2 is caus

Oxidation of Enol Silyl Ethers: Preparation of Aeginetolide, Dihydroactinidiolide, and Actinidiolide

The preparation of the C11-terpenic lactones aeginetolide (1), dihydroactinidiolide (2), and actinidiolide (3) by using 1,3,3-trimethyl-2-(trimethylsiloxy)cyclohexene (9) as a common precursor is discussed.The key steps in the synthetic route involve the sequential m-chloroperbenzoic acid (MCPBA) oxidation and acetylation of 9 and of the siloxy diene 13 derived from 9.