84001-90-1

Basic information

• Product Name: 2-Propenoic acid, 3-(2,4,6-trimethylphenyl)-, ethyl ester, (2E)-
• CAS NO: 84001-90-1
• Molecular Formula: C14H18O2
• Molecular Weight: 218.296
• Mol File: 84001-90-1.mol
• Article Data: 24

Chemical Properties

• CAS DataBase Reference: 2-Propenoic acid, 3-(2,4,6-trimethylphenyl)-, ethyl ester, (2E)-(CAS DataBase Reference)
• NIST Chemistry Reference: 2-Propenoic acid, 3-(2,4,6-trimethylphenyl)-, ethyl ester, (2E)-(84001-90-1)
• EPA Substance Registry System: 2-Propenoic acid, 3-(2,4,6-trimethylphenyl)-, ethyl ester, (2E)-(84001-90-1)

Safety Data

• Hazardous Substances Data: 84001-90-1(Hazardous Substances Data)

Upstream product

• 487-68-3 mesytaldehyde 
• 110795-27-2 (2E)-3-(2,4,6-trimethylphenyl)propenoic acid 
• 105-36-2 ethyl bromoacetate 
• 4028-63-1 iodomesitylene 
• 140-88-5 ethyl acrylate 
• 141-78-6 ethyl acetate 
• 1099-45-2 ethyl (triphenylphosphoranylidene)acetate 
• 769-25-5 2,4,6-trimethylstyrene 
• 623-73-4 diazoacetic acid ethyl ester 
• 4761-00-6 2,4,6-trimethylbenzylbromide 
• 24045-02-1 (benzothiazole-2-sulfonyl)-acetic acid ethyl ester 
• 623-47-2 propynoic acid ethyl ester 
• 108-67-8 1,3,5-trimethyl-benzene 
• 2633-66-1 2-mesitylmagnesium bromide 

Downstream Products

• 80152-88-1 2,2,6,6-tetramethyl-5-(2,4,6-trimethylphenyl)heptan-3-one 
• 80152-86-9 ethyl 4,4-dimethyl-3-(2,4,6-trimethylphenyl)pentanoate 
• 80152-87-0 ethyl 3,3-dimethyl-2-(2,4,6-trimethylphenyl)butanoate 
• 85995-46-6 ethyl (2Z)-3-(2,4,6-trimethylphenyl)-2-propenoate 
• 1332887-90-7 (E)-3-(2,4,6-trimethylphenyl)allyl-2,2,2-trichloroacetimidate 
• 1270437-76-7 1-(2,4,6-trimethylphenyl)-prop-2-en-1-amine 
• 1213356-10-5 (R)-1-(2,4,6-trimethylphenyl)-prop-2-en-1-amine 
• 1213370-88-7 (S)-1-(2,4,6-trimethylphenyl)-prop-2-en-1-amine 
• 866458-10-8 3-(2,4,6-trimethylphenyl)prop-2-en-1-ol 
• 1632992-96-1 (E)-2-(3-bromoprop-1-en-1-yl)-1,3,5-trimethylbenzene 
• 131534-70-8 E-3-(2,4,6-trimethylphenyl)propenal 

Relevant articles and documents

Photoinduced Oxidative Alkoxycarbonylation of Alkenes with Alkyl Formates

A photoinduced oxidative alkoxycarbonylation of alkenes initiated by intermolecular addition of alkoxycarbonyl radicals has been demonstrated. Employing alkyl formates as alkoxycarbonyl radical sources, a range of α,β-unsaturated esters were obtained with good regioselectivity and E selectivity under ambient conditions.

Metal-free domino Cloke-Wilson rearrangement-hydration-dimerization of cyclopropane carbaldehydes: A facile access to oxybis(2-aryltetrahydrofuran) derivatives

In this work, we have demonstrated a metal-free transformation of cyclopropane carbaldehydes to oxybis(2-aryltetrahydrofuran) derivatives via a domino Cloke-Wilson rearrangement-hydration-dimerization sequence. Commercially inexpensive p-toluene sulfonic acid (PTSA) was used as a Br?nsted acid catalyst, and reactions were conducted in an open-flask. Detection of reaction intermediates were carried to get an insight into the reaction pathway.

Determination of the Absolute Configuration of (S)-N-(1-Aryl-allyl)-3,5-dinitrobenzamides and Their Elution Order on Brush-Type Chiral Stationary Phases

A series of ten enantiomerically pure (S)-N-(1-aryl-allyl)-3,5-dinitrobenzamides (S-DNBs) was prepared using enzymatic resolution and chiral chromatography. Enzymatic resolution of corresponding 1-aryl-allylamines using Candida antarctica lipase B (CaLB) was efficient for amines with no steric hindrance near the stereogenic center and S-DNB amides were prepared by acylation of the obtained S-amine. When steric effects interrupted enzymatic resolution, racemic DNB amides were resolved using a brush-type chiral column (CSP-A) developed in our laboratory. Previously reported behavior of CaLB in kinetic resolution of amines was considered a starting point for the determination of absolute configuration (AC). The AC of prepared S-DNB amides was anticipated using the elution order of prepared DNB amides on CSP-A and commercial Whelk-O1 columns and comparison with DNB amides obtained after acylation of (S)-amines. The comparison between experimental electronic circular dichroism (ECD) spectra with those obtained by conformational analysis and ECD calculations of representative compounds allowed us to verify the AC of prepared DNB amides.