84201-67-2

Basic information

• Product Name: 2-Undecen-1-ol, 4,4,5,5,6,6,7,7,8,8,9,9,10,10,11,11,11-heptadecafluoro-, (E)-
• CAS NO: 84201-67-2
• Molecular Formula: C11H5F17O
• Molecular Weight: 476.133
• Mol File: 84201-67-2.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 2-Undecen-1-ol, 4,4,5,5,6,6,7,7,8,8,9,9,10,10,11,11,11-heptadecafluoro-, (E)-(CAS DataBase Reference)
• NIST Chemistry Reference: 2-Undecen-1-ol, 4,4,5,5,6,6,7,7,8,8,9,9,10,10,11,11,11-heptadecafluoro-, (E)-(84201-67-2)
• EPA Substance Registry System: 2-Undecen-1-ol, 4,4,5,5,6,6,7,7,8,8,9,9,10,10,11,11,11-heptadecafluoro-, (E)-(84201-67-2)

Safety Data

• Hazardous Substances Data: 84201-67-2(Hazardous Substances Data)

Upstream product

• 99325-02-7 2-Iodo-4,4,5,5,6,6,7,7,8,8,9,9,10,10,11,11,11-heptadecafluoroundecyl acetate 
• 507-63-1 1-iodoheptadecafluorooctane 
• 591-87-7 Allyl acetate 

Relevant articles and documents

Highly selective synthesis of [(perfluoroalkyl)methyl]oxiranes (by the addition of iodoperfluoroalkanes to allyl acetate)

Mixtures of regioisomeric adducts of monoiodoperfluoroalkanes RF-I (RF = C4F9, C6F13, C8F17) with allyl acetate, RFCH2CHICH2OAc (1a-1c) and rearranged adducts RFCH2CH(OAc)-CH2I (2a-2c), were converted chemoselectively to the corresponding oxiranes RFCH2CH(-O-)CH2 (3a-3c) in yields of 94-96% (total yields of the two-step synthesis starting from RF-I were 85-87%). The chemoselectivity of the oxirane formation appeared to be very dependent on the solvent used. Dependence on the reaction conditions on formation of byproducts RFCH=CHCH2OAc (4a-4c) and RFCH=CHCH2OH (5a-5c) in the epoxidation reaction was studied.