84363-95-1

Basic information

• Product Name: 1-cyclohexyl-2,6-dimethyl-2-vinyl-5-hepten-1-ol
• CAS NO: 84363-95-1
• Molecular Weight: 250.425
• Mol File: 84363-95-1.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: 1-cyclohexyl-2,6-dimethyl-2-vinyl-5-hepten-1-ol(CAS DataBase Reference)
• NIST Chemistry Reference: 1-cyclohexyl-2,6-dimethyl-2-vinyl-5-hepten-1-ol(84363-95-1)
• EPA Substance Registry System: 1-cyclohexyl-2,6-dimethyl-2-vinyl-5-hepten-1-ol(84363-95-1)

Safety Data

• Hazardous Substances Data: 84363-95-1(Hazardous Substances Data)

Upstream product

• 106-24-1 Geraniol 
• 2043-61-0 cyclohexanecarbaldehyde 
• 60699-32-3 (E)-3,7-dimethylocta-2,6-dien-1-yl diethyl phosphate 
• 67883-63-0 (E)-3,7-dimethyl-1-tributylstannylocta-2,6-diene 
• 60699-29-8 (Z)-3,7-dimethylocta-2,6-dien-1-yl diethyl phosphate 
• 5389-87-7 1-chloro-3,7-dimethylocta-2,6-diene 
• 20536-36-1 neryl chloride 
• 6138-90-5 trans-geranyl bromide 

Relevant articles and documents

Stereospecificity in the Lewis acid promoted allylation reaction of 3,3- disubstituted allyltins toward aldehydes

The Lewis acid-promoted reaction of 3,3-disubstituted allyltins toward aldehydes was found to be stereospecific; the (E)-reagent gave syn-products and the (Z)-one gave anti-products. This is in contrast to that of 3-mono- substituted congeners which are k

Chromium(II)-Mediated Stereodivergent Additions of Allylic Phosphates and Halides to Aldehydes

The addition of γ-disubstituted allylchromium(III) reagents to aldehydes proceeds in a stereodivergent manner, in contrast to the case of γ-monosubstituted allylchromium(III) species.The method allows the preparation of a variety of homoallylic alcohols bearing a quaternary center of defined relative configuration in the α-position.The preparation of both stereomeric homoallylic alcohols 13 is possible by using either of the two (E)- or (Z)-allylic precursors.The reaction has been extended to a γ-monosubstituted β-(trimethylsilyl)allylic system.The intermediate allylic chromium(III) reagents can be conveniently prepared from the corresponding phosphates (or chlorides) in DMPU or THF in the presence of catalytic amounts of LiI.

STEREOSELECTIVE ACYCLIC SYNTHESIS VIA ALLYLMETALS: STRUCTURAL DEPENDENCE IN A LEWIS-ACID CATALYZED ADDITION OF ALLYLTINS TO ALDEHYDES

Lewis-acid catalyzed reaction of allyltins with aldehydes at -78 deg C provide homoallyl alcohols with high stereoselectivity; 2-alkenyltins in general provide erythro adducts preferentially with an erithro/threo ratio greater than 12/1, whereas only thre