84487-57-0

Basic information

• Product Name: Benzenamine, N-2-cyclopenten-1-yl-
• CAS NO: 84487-57-0
• Molecular Formula: C11H13N
• Molecular Weight: 159.231
• Mol File: 84487-57-0.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: Benzenamine, N-2-cyclopenten-1-yl-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzenamine, N-2-cyclopenten-1-yl-(84487-57-0)
• EPA Substance Registry System: Benzenamine, N-2-cyclopenten-1-yl-(84487-57-0)

Safety Data

• Hazardous Substances Data: 84487-57-0(Hazardous Substances Data)

Upstream product

• 142-29-0 cyclopentene 
• 622-37-7 Phenyl azide 
• 62-53-3 aniline 
• 98-95-3 nitrobenzene 
• 96-40-2 2-cyclopenten-1-yl chloride 
• 3212-60-0 cyclopent-2-enol 

Downstream Products

• 120474-88-6 tricarbonyl(N-cyclopent-2-en-1-yl-N-phenyl-1-4-η-cyclohexa-1,3-dienecarboxylate)iron 
• 62-53-3 aniline 
• 84487-46-7 ortho-(cyclopent-2-en-1-yl)aniline 

Relevant articles and documents

Method for preparing allylamine compounds

The invention discloses a method for preparing allylamine compounds. The allylamine compounds are synthesized by taking an ionic iron (III) complex which has a molecular formula of [(RNCH2CH2NR)CH][FeBr4] (R is tert-butyl) and contains 1,3-di-tert-butyl imidazoline cation as a catalyst, taking di-tert-butyl peroxide as an oxidant and carrying out oxidative coupling reaction on amine compounds andallyl hydrocarbon compounds. The method disclosed by the invention has wide application range, can be used for aromatic amine containing an electron-withdrawing group, is effective for aromatic aminecontaining an electron-donating group, and is a first case of preparing the allylamine compounds through the oxidative coupling reaction of the amine compounds and the allyl hydrocarbon compounds, which is realized by an iron-based catalyst.

Synthesis of 7-bromo, 7-phenylethynyl, 7-azido, and 7-nitro derivatives of N-acetyl-1,3a,4,8b-tetrahydrocyclopenta[b]indole

7-Bromo-, 7-phenylethynyl-, 7-azido-, 7-nitro-, and 5,7-dinitro-substituted N-acetyl-1,3a,4,8b-tetrahydrocyclopenta[b]indoles have been synthesized starting from anilines and 3-chlorocyclopentene. The NMR spectra of N-acetyl-7-nitro-1,3a,4,8b-tetrahydrocyclopenta[b]indoles displayed no signal doubling typical of the other 7-substituted derivatives.

A Novel Ring-opening Reaction of an Aziridinium-AlCl3 Complex. Reaction of Phenyl Azide with Alkenes in the Presence of AlCl3

Reaction of phenyl azide with alkenes in the presence of ALCl3 gives an aziridinium-AlCl3 complex via an azide-AlCl3 complex; this reaction is followed by ring-opening reactions of the aziridinium-AlCl3 complex to give N-allylanilines and/or N-phenyl-β-chloroamines after work-up with aqueous Na2CO3, but the reaction with cis-cyclo-octene yields a novel aziridine, 9-phenyl-9-azabicyclononane after the work-up.