84557-87-9

Basic information

• Product Name: (E)-1-(6-methylhept-5-en-2-ylidene)-2-phenylhydrazine
• Synonyms: (E)-1-(6-methylhept-5-en-2-ylidene)-2-phenylhydrazine
• CAS NO: 84557-87-9
• Molecular Weight: 216.326
• Mol File: 84557-87-9.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (E)-1-(6-methylhept-5-en-2-ylidene)-2-phenylhydrazine(CAS DataBase Reference)
• NIST Chemistry Reference: (E)-1-(6-methylhept-5-en-2-ylidene)-2-phenylhydrazine(84557-87-9)
• EPA Substance Registry System: (E)-1-(6-methylhept-5-en-2-ylidene)-2-phenylhydrazine(84557-87-9)

Safety Data

• Hazardous Substances Data: 84557-87-9(Hazardous Substances Data)

Upstream product

• 110-93-0 6-Methyl-hept-5-en-2-on 
• 100-63-0 phenylhydrazine 

Downstream Products

• 16262-93-4 5,6-epoxy-6-methyl-2-heptanone 
• 16194-31-3 (+/-)-1,3,3-trimethyl-2,7-dioxabicyclo<2.2.1>heptane 
• 110-93-0 6-Methyl-hept-5-en-2-on 
• 166407-70-1 1,5-dimethyl-1-(phenyldiazenyl)hex-4-enyl hydroperoxide 

Relevant articles and documents

Intramolecular polar [4·+2] cycloadditions of aryl-1-aza-2-azoniaallene salts: Unprecedented reactivity leading to polycyclic protonated azomethine imines

Charged up: In the first example of the title salts undergoing a [4 ·+2]cycloaddition reaction, the azo bond and one aromatic πbond make up the 4πcomponent. This reaction appears to be concerted and provides high yields of protonated azomethine imine products. Substituted alkenes provided products containing all-carbon or nitrogen-bearing quaternary centers in high yield.