84565-69-5

Basic information

• Product Name: (+/-)-[(1S,5R)-2-methyl-5-(1-methylvinyl)cyclohex-2-enyl]benzene
• Synonyms: (+/-)-[(1S,5R)-2-methyl-5-(1-methylvinyl)cyclohex-2-enyl]benzene
• CAS NO: 84565-69-5
• Molecular Weight: 212.335
• Mol File: 84565-69-5.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: (+/-)-[(1S,5R)-2-methyl-5-(1-methylvinyl)cyclohex-2-enyl]benzene(CAS DataBase Reference)
• NIST Chemistry Reference: (+/-)-[(1S,5R)-2-methyl-5-(1-methylvinyl)cyclohex-2-enyl]benzene(84565-69-5)
• EPA Substance Registry System: (+/-)-[(1S,5R)-2-methyl-5-(1-methylvinyl)cyclohex-2-enyl]benzene(84565-69-5)

Safety Data

• Hazardous Substances Data: 84565-69-5(Hazardous Substances Data)

Upstream product

• 57022-47-6 (4S,6S)-4-Isopropenyl-6-methoxy-1-methyl-cyclohexene 
• 98-80-6 phenylboronic acid 
• 7632-16-8 (2S,4S)-carveol 
• 2244-16-8 (S)-p-mentha-6,8-dien-2-one 
• 108-86-1 bromobenzene 
• 121156-22-7 (+)-(R,R)-cis-carveolbenzoate 
• 119905-76-9 (1S,5R)-2-methyl-5-(prop-1-en-2-yl)cyclohex-2-en-1-yl benzoate 
• 84565-82-2 (1'S,5'S)-5'-Isopropenyl-2'-methyl-bicyclohexyl-2,5,2'-triene-1-carboxylic acid 
• 84565-82-2 (S)-5'-Isopropenyl-2'-methyl-bicyclohexyl-2,5,2'-triene-1-carboxylic acid 
• 73524-01-3 cis-Carvyl benzoate 
• 934-56-5 trimethyl(phenyl)stannane 

Relevant articles and documents

Nickel-Catalyzed Arylation of C(sp3)-O Bonds in Allylic Alkyl Ethers with Organoboron Compounds

A nickel-catalyzed cross-coupling of allylic alkyl ethers with organoboron compounds through the cleavage of the inert C(sp3)-O(alkyl) bonds is described. Several types of allylic alkyl ethers can be coupled with various boronic acids or their derivatives to give the corresponding products in good to excellent yields with wide functional group tolerance and excellent regioselectivity. The gram-scale reaction and late-stage modification of biologically active compounds further prove the practicality of this synthetic method.

Stereoselective Phenylation of Allylic Alcohol Derivatives by Palladium-Catalyzed Cross-Coupling with Hypervalent Silicon Complexes

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