84632-32-6Relevant articles and documents
INVESTIGATION ON METHYL GROUP ROTATION IN N,N-DIMETHYLAMIDES BY 1H NMR SPECTRA OF COMPOUNDS MONODEUTERATED IN N-METHYL GROUPS
Gryff-Keller, Adam,Poppe, Leszek
, p. 1049 - 1054 (2007/10/02)
Low temperature 1H NMR spectra of five N,N-bis(monodeuteriomethyl)amides have been measured.It has been observed that the relaxation rates of 2H nuclei in E and Z-CH2D groups are different.Higher relaxation rates of deuterons in E-CH2D groups seem to be caused by their lower rotation rates.