847027-68-3

Basic information

• Product Name: methyl (E/Z)-2-(2-chloromethylphenyl)-2-methoximinoacetate
• Synonyms: methyl (E/Z)-2-(2-chloromethylphenyl)-2-methoximinoacetate
• CAS NO: 847027-68-3
• Molecular Weight: 241.674
• Mol File: 847027-68-3.mol
• Article Data: 1

Chemical Properties

• Boiling Point: 333.0±44.0 °C(Predicted)
• Density: 1.18±0.1 g/cm3(Predicted)
• CAS DataBase Reference: methyl (E/Z)-2-(2-chloromethylphenyl)-2-methoximinoacetate(CAS DataBase Reference)
• NIST Chemistry Reference: methyl (E/Z)-2-(2-chloromethylphenyl)-2-methoximinoacetate(847027-68-3)
• EPA Substance Registry System: methyl (E/Z)-2-(2-chloromethylphenyl)-2-methoximinoacetate(847027-68-3)

Safety Data

• Hazardous Substances Data: 847027-68-3(Hazardous Substances Data)

Upstream product

• 130490-95-8 methyl [2-(chloromethyl)benzoyl]formate 
• 593-56-6 N-methoxylamine hydrochloride 

Downstream Products

• 189813-45-4 (E)-methyl 2-(2-(chloromethyl)phenyl)-2-(methoxyimino)acetate 
• 918162-03-5 C₁₈H₁₅ClF₃NO₄ 

Relevant articles and documents

IMPROVED PROCESS FOR PREPARING O-CHLOROMETHYLPHENYLGLYOXYLIC ESTERS, IMPROVED PROCESS FOR PREPARING (E)-2-(2-CHLOROMETHYLPHENYL)-2-ALKOXIMINOACETIC ESTERS, AND NOVEL INTERMEDIATES FOR THEIR PREPARATION

An improved process for preparing o-chloromethylphenylglyoxylic esters of the formula (I) which comprises converting a compound of the formula (II) by reaction with magnesium into the corresponding Grignard reagent which is then reacted with a compound of the formula (III) to give the compound of the formula (IV) which is then cleaved by reaction with a chloroformic ester of the formula ClCOOR4 or by reaction with phosgene to give the compound of the formula (I), followed by the isolation of the compound of the formula (I), and also an improved process for preparing (E)-2-(2-chloromethylphenyl)- 2-alkoximinoacetic esters of the formula (VII) and intermediates for their preparation.