84782-60-5Relevant articles and documents
New Rearrangement of Phenylseleno- and Trimethylsilylmethyl Groups in 2-Hydroxy-3-trimethylsilylpropyl Selenides
Nishiyama, Hisao,Kitajima, Toshio,Yamamoto, Akiko,Itoh, Kenji
, p. 1232 - 1233 (1982)
2-Hydroxy-3-trimethylsilylpropyl selenides, readily prepared by the reaction of α-phenylselenoaldehydes and trimethylsilylmethyl-lithium, are transformed into primary allylic selenides and β-trimethylsilylpropanals by acid-catalysed dehydroxysilylation accompanied by a phenylseleno-shift, and by silver-induced rearrangement of the trimethylsilylmethyl group, respectively.