847869-90-3

Basic information

• Product Name: poly[[bis(pyridine-κN)copper(II)]-μ3-5-hydroxyisophthalato-κ3O:O':O'']
• CAS NO: 847869-90-3
• Molecular Weight: 401.866
• Mol File: 847869-90-3.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: poly[[bis(pyridine-κN)copper(II)]-μ3-5-hydroxyisophthalato-κ3O:O':O''](CAS DataBase Reference)
• NIST Chemistry Reference: poly[[bis(pyridine-κN)copper(II)]-μ3-5-hydroxyisophthalato-κ3O:O':O''](847869-90-3)
• EPA Substance Registry System: poly[[bis(pyridine-κN)copper(II)]-μ3-5-hydroxyisophthalato-κ3O:O':O''](847869-90-3)

Safety Data

• Hazardous Substances Data: 847869-90-3(Hazardous Substances Data)

Upstream product

• 110-86-1 pyridine 
• 618-83-7 5-Hydroxyisophthalic acid 
• 6046-93-1 copper(II) acetate monohydrate 

Relevant articles and documents

Poly[[bis(pyridine-kN)copper(II)]-μ35-hydroxyisophthalato- k3O:O':O ]

The design and synthesis of supramolecular coordination in Poly[[bis(pyridine-κN)copper(II)]-μ3-5-hydroxyisophthal ato-κ3O:O′:O″ polymer networks was investigated. In this complex the Cu atoms were found to be coordinated by two N atoms from the pyridine ligands and by three O atoms from hydroxyisophthalate ligands in a highly distorted triangular bipyramidal environment. The dihedral angle between the two py rings that coordinate to the same Cu atom is 75.41°. The results show that dihedral angle between two π-π interacting py rings is 22.83° and the distance between the centroids of the two py rings is 4.131 A.