84904-61-0

Basic information

• Product Name: o-(1'-butenyl)bromobenzene
• Synonyms: o-(1'-butenyl)bromobenzene
• CAS NO: 84904-61-0
• Molecular Weight: 211.101
• Mol File: 84904-61-0.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: o-(1'-butenyl)bromobenzene(CAS DataBase Reference)
• NIST Chemistry Reference: o-(1'-butenyl)bromobenzene(84904-61-0)
• EPA Substance Registry System: o-(1'-butenyl)bromobenzene(84904-61-0)

Safety Data

• Hazardous Substances Data: 84904-61-0(Hazardous Substances Data)

Upstream product

• 6228-47-3 n-propyltriphenylphosphonium bromide 
• 6630-33-7 ortho-bromobenzaldehyde 
• 75-16-1 methylmagnesium bromide 
• 16666-78-7 propylidenetriphenylphosphorane 

Downstream Products

• 1370529-55-7 C₁₇H₁₈O 
• 1370529-60-4 C₁₇H₁₈O 
• 1192805-45-0 N-p-toluenesulfonyl-2-ethylindole 
• 84904-45-0 t-butyl-o-(1'-butenyl)phenyl ketoxime 

Relevant articles and documents

Rhodium-catalyzed intramolecular hydroacylation of 1,2-disubstituted alkenes for the synthesis of 2-substituted indanones

The intramolecular hydroacylation of 1,2-disubstituted alkenes was considered to be a challenging task due to the side reactions resulted from the lack of additional substituent at 1-position and the low activity caused by the steric hindrance of substituent at 2-position, and an asymmetric version has not been considered possible due to problems associated with the racemization of the products. We have partially solved these problems. Catalyzed by an activated diphosphine-Rh complex and reacted in a selected dihalogenated solvent, the intramolecular hydroacylation of o-(2-arylvinyl)benzaldehydes provided the corresponding 2-aryl-1-indanones in high yields, and its asymmetric variant using o-(2-alkylvinyl)benzaldehydes afforded chiral 2-alkyl-1-indanones in high yields and with moderate enantioselectivities.

Photochemical studies on aromatic γ,δ-epoxy ketones: Efficient synthesis of benzocyclobutanones and indanones

Irradiation of terminal aromatic γ,δ-epoxy ketones with a 450 W UV lamp led to Norrish type II cyclization/semi-pinacol rearrangement cascade reaction which formed the benzocyclobutanones containing a full-carbon quaternary center, whereas irradiation of substituted aromatic γ,δ-epoxy ketones led to the indanones through a photochemical epoxy rearrangement and 1,5-biradicals cyclization tandem reaction.