849590-67-6

Basic information

• Product Name: Benzenemethanol, a-(1E)-1-butenyl-, acetate
• CAS NO: 849590-67-6
• Molecular Formula: C13H16O2
• Molecular Weight: 204.269
• Mol File: 849590-67-6.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Benzenemethanol, a-(1E)-1-butenyl-, acetate(CAS DataBase Reference)
• NIST Chemistry Reference: Benzenemethanol, a-(1E)-1-butenyl-, acetate(849590-67-6)
• EPA Substance Registry System: Benzenemethanol, a-(1E)-1-butenyl-, acetate(849590-67-6)

Safety Data

• Hazardous Substances Data: 849590-67-6(Hazardous Substances Data)

Upstream product

• 57078-04-3 (E)-1-phenyl-2-penten-1-ol 
• 108-24-7 acetic anhydride 
• 1576-86-9 2-pentenal 
• 108-86-1 bromobenzene 
• 1576-87-0 trans-2-pentenal 
• 75-36-5 acetyl chloride 
• 100-52-7 benzaldehyde 

Downstream Products

• 1608-27-1 ((1E)-penta-1,3-dien-1-yl)benzene 
• 94421-30-4 (E)-1-phenyl-1-penten-3-ol acetate 

Relevant articles and documents

Size-Exclusion Borane-Catalyzed Domino 1,3-Allylic/Reductive Ireland–Claisen Rearrangements: Impact of the Electronic and Structural Parameters on the 1,3-Allylic Shift Aptitude

The reductive Ireland–Claisen rearrangement through borane-mediated hydrosilylation is reported. The method employs a borane catalyst with a special structural design and affords access to synthetically relevant products with high diastereoselectivity. Depending on electronic and structural parameters, the reaction can be coupled with a 1,3-allylic shift, thus the valence isomer of the Ireland–Claisen product is formed.