85006-08-2 Usage
General Description
o-Tolyl 3-methylsalicylate is a chemical compound commonly used as a fragrance ingredient in perfumes and personal care products. It is also known by the trade name "methyl anthranilate" and has a sweet, fruity odor reminiscent of grapes. This chemical is used to add a pleasant scent to a wide range of products, including soaps, shampoos, lotions, and detergents. It is also used as a flavoring agent in food products and as a mosquito repellent in some insecticides. While it is generally considered safe for use in these applications, it should be handled with care and stored according to safety guidelines to avoid potential hazards.
Check Digit Verification of cas no
The CAS Registry Mumber 85006-08-2 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 8,5,0,0 and 6 respectively; the second part has 2 digits, 0 and 8 respectively.
Calculate Digit Verification of CAS Registry Number 85006-08:
(7*8)+(6*5)+(5*0)+(4*0)+(3*6)+(2*0)+(1*8)=112
112 % 10 = 2
So 85006-08-2 is a valid CAS Registry Number.
InChI:InChI=1/C15H14O3/c1-10-6-3-4-9-13(10)18-15(17)12-8-5-7-11(2)14(12)16/h3-9,16H,1-2H3
85006-08-2Relevant articles and documents
Rhodium-Catalyzed Carbonylative Synthesis of Aryl Salicylates from Unactivated Phenols
Ai, Han-Jun,Zhang, Youcan,Zhao, Fengqian,Wu, Xiao-Feng
supporting information, p. 6050 - 6054 (2020/10/02)
A rhodium-catalyzed carbonylative transformation of unactivated phenols to aryl salicylates is described. This protocol is characterized by utilizing 1,3-rhodium migration as the key step to provide direct access to synthesize ohydroxyaryl esters. Various desired aryl o-hydroxybenzoates were produced in moderate to excellent yields with bis(dicyclohexylphosphino)ethane (DCPE) as the ligand. Interestingly, diphenyl carbonate was formed as the main product when 1,3-bis(diphenylphosphino)propane (DPPP) was used as the ligand. A plausible reaction mechanism is proposed.
