85029-27-2Relevant articles and documents
Oxidant controlled Pd-catalysed selective oxidation of primary alcohols
Liu, Chao,Tang, Shan,Lei, Aiwen
, p. 1324 - 1326 (2013)
The oxidant controlled palladium catalysed selective oxidation of primary alcohols to aldehydes or esters was investigated. The electronic properties of the benzylic alcohols and the structure of the oxidant are both important factors in controlling the selectivity between aldehydes and esters. A covalent benzyl ligand derived from BnCl provides η3 coordination to the Pd centre. This covalent ligand is the key to the selective oxidative esterification of primary alcohols.
The collision induced loss of carbon monoxide from deprotonated benzyl benzoate in the gas phase. an anionic 1,2-Wittig type rearrangement
Chia, C.S. Brian,Taylor, Mark S.,Dua, Suresh,Blanksby, Stephen J.,Bowie, John H.
, p. 1435 - 1441 (2007/10/03)
The ion PhCO2--CHPh, upon collision activation, undergoes competitive losses of CO and CO2 of which the former process produces the base peak of the spectrum. Product ion and substituent effect (Hammett) studies indicate t
Lithium Tungsten Dioxide Promoted Claisen-Tishchenko Condensation of Aromatic and Aliphatic Aldehydes
Villacorta, Gilberto M.,Filippo, Joseph San
, p. 1151 - 1154 (2007/10/02)
Lithium tungsten dioxide, LiWO2, has been shown to be a useful catalyst for effecting the Claisen-Tishchenko condensation of aldehydes under heterogeneous conditions.
