85121-45-5Relevant articles and documents
Synthesis of (+/-)-karahana ether and a (+/-)-labdadienoic acid by the electrophilic cyclization of epoxy allylsilanes
Armstrong, Rosemary J.,Weiler, Larry
, p. 584 - 596 (2007/10/02)
The epoxy allylsilanes 7 and 16 were synthesized by stereoselective routes from β-keto esters and cyclized with Lewis acids in good yield.The monocyclic product from 7 was converted into (+/-)-karahana ether (10), and the bicyclic product from 20 was used in a synthesis of the 3-hydroxylabdadienoic acid 24b.