851915-19-0Relevant articles and documents
Investigations into the mechanism of activation and initiation of ethylene polymerization by bis(imino)pyridine cobalt catalysts: Synthesis, structures, and deuterium labeling studies
Humphries, Martin J.,Tellmann, Kilian P.,Gibson, Vernon C.,White, Andrew J. P.,Williams, David J.
, p. 2039 - 2050 (2008/10/09)
The activation of bis(imino)pyridine cobalt(II) precatalysts by MAO leads initially to a bis(imino)pyridine cobalt(I) cationic species with no cobalt-C(alkyl) bond into which insertion can occur. Mechanistic studies have shown that the initiation of polym